2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

Base Information

Chemical Name:2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone
CAS No.:122271-48-1
Molecular Formula:C₁₅H₂₄O₅Si
Molecular Weight:312.438
Hs Code.:

Synonyms:2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

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Technology Process of 2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

There total 3 articles about 2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 22028-15-5
2,3-Dimethoxy-5-(hydroxymethyl)-2,5-cyclohexadiene-1,4-dione

: 18162-48-6
tert-butyldimethylsilyl chloride

: 122271-48-1
2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; for 0.5h;
DOI:10.1021/jo00278a023

Reference yield:

: 122271-46-9
3-hydroxy-4,5-dimethoxybenzyl alcohol

: 122271-48-1
2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / sodium acetate, potassium nitrosodisulfonate (Fremy's salt) / methanol; H₂O

2: 98 percent / diisopropylethylamine / dimethylformamide / 0.5 h

With potassium nitrososulfonate; sodium acetate; N-ethyl-N,N-diisopropylamine; In methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00278a023

Reference yield:

: 111394-55-9
3-<(tert-butyldimethylsilyl)oxy>-4,5-dimethoxybenzyl alcohol

: 122271-48-1
2-<<(tert-butyldimethylsilyl)oxy>methyl>-5,6-dimethoxy-1,4-benzoquinone

Guidance literature:: Multi-step reaction with 3 steps

1: 75 percent / tetrabutylammonium fluoride / tetrahydrofuran / 0.17 h

2: 80 percent / sodium acetate, potassium nitrosodisulfonate (Fremy's salt) / methanol; H₂O

3: 98 percent / diisopropylethylamine / dimethylformamide / 0.5 h

With potassium nitrososulfonate; tetrabutyl ammonium fluoride; sodium acetate; N-ethyl-N,N-diisopropylamine; In tetrahydrofuran; methanol; water; N,N-dimethyl-formamide;
DOI:10.1021/jo00278a023