Butyldiethyliodostannane

Base Information

• Chemical Name: Butyldiethyliodostannane
• CAS No.: 17563-48-3
• Molecular Formula: C8H19ISn
• Molecular Weight: 360.86
• Hs Code.: 2931900090
• Mol file: 17563-48-3.mol

Synonyms:n-Butyldiethyltin iodide;Butyldiethyltin iodide;Tin,butyldiethyliodo;Stannane,butyldiethyliodo;n-Butyl-diaethyl-zinniodid;

Chemical Property of Butyldiethyliodostannane

Chemical Property:

• Vapor Pressure: 0.0359mmHg at 25°C
• Boiling Point: 249.6°C at 760 mmHg
• Flash Point: 104.8°C
• PSA: 0.00000
• LogP: -0.87850

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s): A poison. TWA 0.1 mg(Sn)/m³; STEL 0.2 mg/m³ (skin)
• Hazard Codes: A poison. TWA 0.1 mg(Sn)/m3; STEL 0.2 mg/m3 (skin)

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Butyldiethyliodostannane

There total 3 articles about Butyldiethyliodostannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

butyltriethylstannane (17582-53-5) → n-Butyl-diaethyl-zinniodid (17563-48-3)

Guidance literature:

With iodine; byproducts: C2H5I; mechanism discussed;; Kinetics;

DOI:10.1016/S0022-328X(00)91016-7 DOI:10.1016/S0022-328X(00)91017-9 DOI:10.1016/S0022-328X(00)86992-2

Reference yield:

1-triethylstannylbut-3-ene-1-yne (994-98-9) → n-Butyl-diaethyl-zinniodid (17563-48-3)

Guidance literature:

Multi-step reaction with 2 steps

1: n-butyllithium / diethyl ether

2: I₂

With n-butyllithium; I₂; In diethyl ether;

Reference yield:

→ n-Butyl-diaethyl-zinniodid (17563-48-3)

Guidance literature:

Diaethyl-zinn, n-Butyliodid, im geschl. Rohr, 140grad;

DOI:10.1016/S0022-328X(00)83167-8

upstream raw materials:

butyltriethylstannane

1-triethylstannylbut-3-ene-1-yne

Refernces

• 1、 Boue, S,Gielen, M,Nasielski, J. "Mechanisms of the rupture of the carbon-tin bond by halogens II. Free-radical substitution in solution". . p. 461 - 479. Retrieved 2008/10/08.