Stannane, butyltriethyl-

Base Information

• Chemical Name: Stannane, butyltriethyl-
• CAS No.: 17582-53-5
• Molecular Formula: C10H24Sn
• Molecular Weight: 263.011
• Hs Code.: 2931900090
• NSC Number: 203222
• DSSTox Substance ID: DTXSID20170032
• Mol file: 17582-53-5.mol

Synonyms:Stannane, butyltriethyl-;butyl(triethyl)stannane;Butyl triethyltin;17582-53-5;Butyltriethylstannane;Stannane,butyltriethyl-;triethylbutylstannane;NSC203222;Stannane, triethyl-, n-butyl-;DTXSID20170032;UVPJFOOYINQGPP-UHFFFAOYSA-N;NSC 203222;NSC-203222

Chemical Property of Stannane, butyltriethyl-

Chemical Property:

• Vapor Pressure: 0.133mmHg at 25°C
• Boiling Point: 224.9 °C at 760 mmHg
• Flash Point: 89.8 °C
• PSA: 0.00000
• Density: 1.1457 g/cm3
• LogP: 4.29500
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 6
• Exact Mass: 264.090003
• Heavy Atom Count: 11
• Complexity: 76.6

Purity/Quality:

99.5% ^*data from raw suppliers

MONOBUTYLTRIETHYLTIN 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCC[Sn](CC)(CC)CC

Technology Process of Stannane, butyltriethyl-

There total 31 articles about Stannane, butyltriethyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

n-butyl magnesium bromide (693-03-8) + triethyltin hydroxide (994-32-1) → butyltriethylstannane (17582-53-5)

Guidance literature:

In diethyl ether;

Reference yield: 88.0%

ethyl bromide (74-96-4) + Trichlorbutylstannan (1118-46-3) → butyltriethylstannane (17582-53-5)

Guidance literature:

With magnesium; In not given; Sonication; mixt. of tin derivative, Mg turnings, solvent (Et2O or THF) and few drops of organic bromide was sonicated (ultrasound, 47 kHz, 300W), soln. of organic bromide was added; washed with brine, extd. with Et2O, dried over MgSO4, evapd. in vac., column chromy. (neutral alumina or silica gel, petroleum ether);

DOI:10.1016/j.jorganchem.2009.03.030

Reference yield: 85.0%

1-iodo-butane (542-69-8) + chlorotriethylstannane (994-31-0) → butyltriethylstannane (17582-53-5)

Guidance literature:

With zinc; In tetrahydrofuran; water; under air atm., at room temp., cosolvent media: H2O(NH4Cl)/THF/Zn, alkyliodide was added dropwise to the alkyl tin halide in solvent mixt. over 15 min, reaction time 1.0 h; Zn was filtered off, aq. phase was extd. three times with n-pentane, organic phase was washed with sat. aq. NaCl and dried over MgSO4, solvent was removed, crude oil was distilled under vac.; (119Sn NMR monitoring);

DOI:10.1016/S0022-328X(00)00388-0

upstream raw materials:

n-butyl magnesium bromide

tri(n-butyl)aluminium

triethylstannane

chloroethane

Downstream raw materials:

n-Butyl-diaethyl-zinniodid