(2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol

Base Information

Chemical Name:(2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol
CAS No.:18665-81-1
Molecular Formula:C₁₅H₂₆O
Molecular Weight:222.371
Hs Code.:
UNII:6SQ6UBE8RC
Nikkaji Number:J818.895E
Metabolomics Workbench ID:166989

Synonyms:Monocyclofarnesol;Monocyclofarnesol-;6SQ6UBE8RC;UNII-6SQ6UBE8RC;(2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol;5-(2,6,6-Trimethyl-1-cyclohexenyl)-3-methyl-2-penten-1-ol;2-Penten-1-ol, 3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-;3-Methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol;2-Penten-1-ol, 3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-, (2E)-;18665-81-1;SCHEMBL10818080;(E)-3-Methyl-5-(2,6,6-trimethyl-1-cyclohexenyl)-2-penten-1-ol;(E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexenyl)-pent-2-en-1-ol

Suppliers and Price of (2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemical Property of (2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol

Chemical Property:

XLogP3:3.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:222.198365449
Heavy Atom Count:16
Complexity:295

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=C(C(CCC1)(C)C)CCC(=CCO)C
Isomeric SMILES:CC1=C(C(CCC1)(C)C)CC/C(=C/CO)/C

Technology Process of (2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol

There total 7 articles about (2E)-3-methyl-5-(2,6,6-trimethyl-1-cyclohexen-1-yl)-2-penten-1-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 42569-33-5
ethyl (E)-3-methyl-5-(2',6',6'-trimethylcyclohex-1'-en-1'-yl)pent-2-enoate

: 18665-81-1
(E)-3-methyl-5-(2',6',6'-trimethylcyclohex-1'-en-1'-yl)pent-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In toluene; at 0 ℃;
DOI:10.1016/S0040-4039(00)00639-0

Reference yield: 83.4%

: 4179-00-4
Methyl (E)-3-methyl-5-(2,6,6-trimethylcyclohexen-1-yl)-2-pentenoate

: 18665-81-1
(E)-3-methyl-5-(2',6',6'-trimethylcyclohex-1'-en-1'-yl)pent-2-en-1-ol

Guidance literature:: With diisobutylaluminium hydride; In tetrahydrofuran; -78 deg C, 2 h; to -10 deg C, 4 h;
DOI:10.1002/hlca.19940770309

Reference yield:

: 17283-81-7
4-(2,6,6-Trimethyl-cyclohex-1-enyl)-butan-2-on

: 18665-81-1
(E)-3-methyl-5-(2',6',6'-trimethylcyclohex-1'-en-1'-yl)pent-2-en-1-ol

Guidance literature:: Multi-step reaction with 2 steps

1: 76 percent / LiHMDS / tetrahydrofuran / 5 h / Heating

2: 100 percent / DIBALH / toluene / 0 °C

With diisobutylaluminium hydride; lithium hexamethyldisilazane; In tetrahydrofuran; toluene; 1: Horner-Emmons olefination;
DOI:10.1246/bcsj.78.1197