(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside

Base Information

• Chemical Name: (1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside
• CAS No.: 88897-27-2
• Molecular Formula: C₆₈H₆₁N₃O₁₈S₃
• Molecular Weight: 1304.44
• Mol file: 88897-27-2.mol

Synonyms:(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside

Chemical Property of (1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside

There total 1 articles about (1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

1-N-3',4',5,6-tetra-O-benzoyl-1,3,2'-tri-N-p-tolylsulfonylparomamine (88897-26-1) → (1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside (88897-27-2) + 1-N-3',4',5,6-tetra-O-benzoyl-6'-O-methylthiomethyl-1,3,2'-tri-N-p-tolylsulfonylparomamine (92734-24-2)

Guidance literature:

With pyridine; dimethyl sulfoxide; dicyclohexyl-carbodiimide; trifluoroacetic acid; In benzene; for 1.5h; Ambient temperature;

DOI:10.1016/0008-6215(84)85280-5

Reference yield:

(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside (88897-27-2) → (1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3-O-benzoyl-2,4-dideoxy-2-p-tolylsulfonamido-β-L-threo-hex-4-enodialdo-1,5-pyranoside (92734-25-3)

Guidance literature:

With triethylamine; In dichloromethane; for 0.5h; Yield given; Ambient temperature;

DOI:10.1016/0008-6215(84)85280-5

Reference yield:

(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2-deoxy-2-p-tolylsulfonamido-α-D-gluco-hexodialdo-1,5-pyranoside (88897-27-2) + ethyl (triphenylphosphoranylidene)acetate (1099-45-2) → E-ethyl <(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2,6,7-trideoxy-2-p-tolylsulfonamido-α-D-gluco-oct-6-enopyranosid>uronate (88897-28-3)

Guidance literature:

In benzene; Yield given; Ambient temperature;

DOI:10.1016/0008-6215(84)85280-5

upstream raw materials:

1-N-3',4',5,6-tetra-O-benzoyl-1,3,2'-tri-N-p-tolylsulfonylparomamine

Downstream raw materials:

(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3-O-benzoyl-2,4-dideoxy-2-p-tolylsulfonamido-β-L-threo-hex-4-enodialdo-1,5-pyranoside

E-ethyl <(1-N-5,6-di-O-benzoyl-2-deoxy-1,3-di-N-p-tolylsulfonylstreptamin-4-yl) 3,4-di-O-benzoyl-2,6,7-trideoxy-2-p-tolylsulfonamido-α-D-gluco-oct-6-enopyranosid>uronate