C₃₃H₄₃NO₆Si

Base Information

Chemical Name:C₃₃H₄₃NO₆Si
CAS No.:1582753-05-6
Molecular Formula:C₃₃H₄₃NO₆Si
Molecular Weight:577.793
Hs Code.:

C<sub>33</sub>H<sub>43</sub>NO<sub>6</sub>Si

Synonyms:C₃₃H₄₃NO₆Si

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Chemical Property of C₃₃H₄₃NO₆Si

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Technology Process of C₃₃H₄₃NO₆Si

There total 11 articles about C₃₃H₄₃NO₆Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (R)-3-methylcyclohex-2-en-1-yl (5S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-5-(triethylsilyl)oxy-3-hydroxyhexanoate

: 1582753-05-6
C₃₃H₄₃NO₆Si

Guidance literature:: Multi-step reaction with 10 steps

1.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; pyridine / tetrahydrofuran; dimethyl sulfoxide / 6 h / Inert atmosphere

2.1: trifluoroacetic acid / dichloromethane; methanol / 0.5 h / 0 °C

3.1: dirhodium tetraacetate / benzene / 0.08 h / Reflux; Inert atmosphere

4.1: tris(triphenylphosphine)rhodium(l) chloride; triphenylphosphine; isopropyl alcohol / 1,4-dioxane / 0.5 h / 60 °C / Inert atmosphere

5.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

5.2: 0.58 h / -78 - 20 °C / Inert atmosphere

6.1: methanol / benzene; hexane / 0.08 h / 0 °C / Inert atmosphere

7.1: diisobutylaluminium hydride / hexane; dichloromethane / 3 h / -78 °C / Inert atmosphere

8.1: Dess-Martin periodane / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

9.1: N,N,N',N'-tetramethylguanidine / 10 h / Inert atmosphere

10.1: sulfuric acid / 2 h / 0 °C

With pyridine; methanol; dirhodium tetraacetate; tris(triphenylphosphine)rhodium(l) chloride; sulfuric acid; diisobutylaluminium hydride; Dess-Martin periodane; triphenylphosphine; isopropyl alcohol; trifluoroacetic acid; lithium diisopropyl amide; N,N,N',N'-tetramethylguanidine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; 1,4-dioxane; methanol; hexane; dichloromethane; dimethyl sulfoxide; benzene; 8.1: |Dess-Martin Oxidation;
DOI:10.1021/ol500657f

Reference yield:

: 905589-27-7
(3S)-4-(tert-butyldiphenylsilyl)oxy-3-(triethylsilyl)oxy-butyraldehyde

: 1582753-05-6
C₃₃H₄₃NO₆Si

Guidance literature:: Multi-step reaction with 11 steps

1.1: lithium hexamethyldisilazane / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

2.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; pyridine / tetrahydrofuran; dimethyl sulfoxide / 6 h / Inert atmosphere

3.1: trifluoroacetic acid / dichloromethane; methanol / 0.5 h / 0 °C

4.1: dirhodium tetraacetate / benzene / 0.08 h / Reflux; Inert atmosphere

5.1: tris(triphenylphosphine)rhodium(l) chloride; triphenylphosphine; isopropyl alcohol / 1,4-dioxane / 0.5 h / 60 °C / Inert atmosphere

6.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

6.2: 0.58 h / -78 - 20 °C / Inert atmosphere

7.1: methanol / benzene; hexane / 0.08 h / 0 °C / Inert atmosphere

8.1: diisobutylaluminium hydride / hexane; dichloromethane / 3 h / -78 °C / Inert atmosphere

9.1: Dess-Martin periodane / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

10.1: N,N,N',N'-tetramethylguanidine / 10 h / Inert atmosphere

11.1: sulfuric acid / 2 h / 0 °C

With pyridine; methanol; dirhodium tetraacetate; tris(triphenylphosphine)rhodium(l) chloride; sulfuric acid; diisobutylaluminium hydride; Dess-Martin periodane; triphenylphosphine; isopropyl alcohol; trifluoroacetic acid; lithium hexamethyldisilazane; lithium diisopropyl amide; N,N,N',N'-tetramethylguanidine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; 1,4-dioxane; methanol; hexane; dichloromethane; dimethyl sulfoxide; benzene; 9.1: |Dess-Martin Oxidation;
DOI:10.1021/ol500657f

Reference yield:

: 1582752-84-8
(R)-3-methylcyclohex-2-en-1-yl (S)-6-(tert-butyldiphenylsilyl)oxy-2-diazo-3-oxo-5-(triethylsilyl)oxyhexanoate

: 1582753-05-6
C₃₃H₄₃NO₆Si

Guidance literature:: Multi-step reaction with 9 steps

1.1: trifluoroacetic acid / dichloromethane; methanol / 0.5 h / 0 °C

2.1: dirhodium tetraacetate / benzene / 0.08 h / Reflux; Inert atmosphere

3.1: tris(triphenylphosphine)rhodium(l) chloride; triphenylphosphine; isopropyl alcohol / 1,4-dioxane / 0.5 h / 60 °C / Inert atmosphere

4.1: lithium diisopropyl amide / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

4.2: 0.58 h / -78 - 20 °C / Inert atmosphere

5.1: methanol / benzene; hexane / 0.08 h / 0 °C / Inert atmosphere

6.1: diisobutylaluminium hydride / hexane; dichloromethane / 3 h / -78 °C / Inert atmosphere

7.1: Dess-Martin periodane / dichloromethane / 2 h / 0 - 20 °C / Inert atmosphere

8.1: N,N,N',N'-tetramethylguanidine / 10 h / Inert atmosphere

9.1: sulfuric acid / 2 h / 0 °C

With methanol; dirhodium tetraacetate; tris(triphenylphosphine)rhodium(l) chloride; sulfuric acid; diisobutylaluminium hydride; Dess-Martin periodane; triphenylphosphine; isopropyl alcohol; trifluoroacetic acid; lithium diisopropyl amide; N,N,N',N'-tetramethylguanidine; In tetrahydrofuran; 1,4-dioxane; methanol; hexane; dichloromethane; benzene; 7.1: |Dess-Martin Oxidation;
DOI:10.1021/ol500657f