1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride

Base Information

• Chemical Name: 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride
• CAS No.: 1380579-83-8
• Molecular Formula: C₃₅H₄₇N₂O₂*Cl
• Molecular Weight: 563.223
• Mol file: 1380579-83-8.mol

Synonyms:1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride

Chemical Property of 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride

There total 1 articles about 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

orthoformic acid triethyl ester (122-51-0) + N,N′-bis(3,5-di-tert-butyl-2-hydroxy-phenyl)-1,2-phenylenediamine (251326-26-8) → 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride (1380579-83-8)

Guidance literature:

With hydrogenchloride; acetic acid; at 60 ℃; for 1h;

DOI:10.1039/c3dt52342j

Reference yield: 100.0%

1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride (1380579-83-8) + cyclohexylamine (108-91-8,157973-60-9) + platinum(II) chloride (10025-65-7) → C41H57N3O2Pt

Guidance literature:

With potassium carbonate; at 100 ℃; for 12h; Inert atmosphere; Schlenk technique;

DOI:10.1021/om5003446

Reference yield: 79.0%

(DME)Mo(NMes)2Cl2 + 1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride (1380579-83-8) → C53H66MoN4O2

Guidance literature:

1,3-bis(3,5-di-tert-butyl-2-hydroxyphenyl)-1H-benzo[d]imidazol-3-ium chloride; With triethylamine; In tetrahydrofuran; for 0.5h; Inert atmosphere; Glovebox;

(DME)Mo(NMes)₂Cl₂; In tetrahydrofuran; at 20 ℃; for 16h; Inert atmosphere; Glovebox;

DOI:10.1021/acs.organomet.9b00472

upstream raw materials:

orthoformic acid triethyl ester

N,N′-bis(3,5-di-tert-butyl-2-hydroxy-phenyl)-1,2-phenylenediamine