Platinum(II) dichloride

Base Information

• Chemical Name: Platinum(II) dichloride
• CAS No.: 10025-65-7
• Molecular Formula: Cl₂Pt
• Molecular Weight: 265.986
• Hs Code.: 28439090
• UNII: 896SQ4TDHW
• Nikkaji Number: J96.445J
• Mol file: 10025-65-7.mol

Synonyms:PLATINOUS DICHLORIDE;PLATINUM(II) DICHLORIDE;PLATINOUS CHLORIDE [MI];PLATINOUS CHLORIDE [HSDB];PLATINOUS CHLORIDE [WHO-DD];AKOS015903848;P1920;Platinum(II) chloride, =99.9% Trace metals grade

Chemical Property of Platinum(II) dichloride

Chemical Property:

• Appearance/Colour: Olive green crystals
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 581 °C (dec.)(lit.)
• PSA: 0.00000
• Density: 6.05 g/mL at 25 °C
• LogP: -5.99450
• Storage Temp.: Store below +30°C.
• Water Solubility.: INSOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 264.902500
• Heavy Atom Count: 3
• Complexity: 0

Purity/Quality:

Platinumchloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): C; Xi
• Hazard Codes: C,Xi
• Statements: 34-42/43-36/37/38-43
• Safety Statements: 22-26-36/37/39-45-27-24-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Pt+2]
• Uses: Platinum chloride is a useful inorganic reagent which has been used in the preparation and characterization of Ru-Pt core-shell nanoparticles. Platinum (II) chloride is a catalyst used for a variety of C-C bond, C-O bond, and C-N bond formation.

Technology Process of Platinum(II) dichloride

There total 48 articles about Platinum(II) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dihydrogen hexachloroplatinate(IV) hexahydrate → platinum(IV) chloride (13454-96-1) + platinum(II) chloride (10025-65-7)

Guidance literature:

heating in dry air at 200°C for 4.5 h;

Reference yield:

platinum (7440-06-4) → Iodine monochloride (7790-99-0) + platinum(II) chloride (10025-65-7)

Guidance literature:

With iodine; In not given; at room temp.;

Reference yield:

cis-{Pt(dimethylsulfoxide)(ammonia)Cl2} (20647-46-5,77715-39-0,22872-00-0,22871-99-4,31169-08-1) → dimethyl sulfoxide (67-68-5,8070-53-9) + platinum(II) chloride (10025-65-7)

Guidance literature:

In solid; byproducts: NH3; a sample was heated up to 500 °C with a heating rate 20 °/min (DTA expt.); not isolated, detected by X-ray powder diffraction;

DOI:10.1007/BF01912702

upstream raw materials:

chlorine

platinum

lead

sulfuryl dichloride

Downstream raw materials:

{(triphenylphosphine)ClPd(μ-Cl)2PtCl(triphenylphosphine)}

dichlorobis(triethylphosphine)platinum

{platinum(II)(2-phenylquinazoline-(3H)-4-one-3-CH₂COO)2}

cis-dichlorobis(triethylphosphine)platinum(II)

Refernces

• 1、 Bridgeman, Adam J.,Cavigliasso, Germán,Harris, Neil,Young, Nigel A.. "A matrix isolation and DFT study of the generation and characterization of monomeric vapour phase platinum chlorides". . p. 319 - 326. Retrieved 2002.
• 2、 Barta Holló,Szilágyi,Várhelyi, Cs.,Hunyadi,Nagy,Tihi,Goga,Papp,Szalay,Pokol. "Synthesis, physico-chemical characterization and bacteriostatic study of Pt complexes with substituted amine ligands". . p. 1733 - 1741. Retrieved 2017.
• 3、 Semenova,Chusova,Titov. "Thermodynamic characteristics of thermal dissociation of platinum dichloride". . p. 1387 - 1390. Retrieved 2005.
• 4、 Richard, M. A.,Pancirov, R. J.. "". . p. 825 - 834. Retrieved 1987.