tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI)

Base Information

• Chemical Name: tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI)
• CAS No.: 115509-89-2
• Molecular Formula: C₄MoN₄O₃*2C₂₄H₂₀P
• Molecular Weight: 926.802
• Mol file: 115509-89-2.mol

Synonyms:tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI)

Chemical Property of tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI)

There total 3 articles about tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tetraphenylphosphonium oxopentacyanomolybdate(IV) (86568-26-5) → tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI) (115509-89-2)

Guidance literature:

With oxygen; In dichloromethane; stirring (O2-atmosphere, 30 min); pptn. on addn. of diethyl ether, recrystn. (CH3CN/diethyl ether); elem. anal.;

Reference yield:

tris(tetraphenylphosphonium) pentacyanooxomolybdate(IV) heptahydrate + oxygen (80937-33-3) → tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI) (115509-89-2)

Guidance literature:

In neat (no solvent, solid phase); byproducts: (PPh4)CN, H2O; Mo-complex was reacted with O2 at 323+/-1 K; monitored by IR; Kinetics;

DOI:10.1039/b202654f

Reference yield:

bis(tetraphenylphosphonium) potassium pentacyanooxomolybdate(IV) pentahydrate + oxygen (80937-33-3) → tetraphenylphosphonium oxoperoxotetracyanomolybdate(VI) (115509-89-2)

Guidance literature:

In neat (no solvent, solid phase); byproducts: KCN, H2O; Mo-complex was reacted with O2 at 323+/-1 K; monitored by IR; Kinetics;

DOI:10.1039/b202654f

upstream raw materials:

tetraphenylphosphonium oxopentacyanomolybdate(IV)

oxygen

Downstream raw materials:

(PPh₄)4Mo₈O₂₆

2P(C₆H₅)4⁽¹⁺⁾*Mo₂O₇^(2-)={P(C₆H₅)4}2{Mo₂O₇}

tetraphenylphosphonium oxopentacyanomolybdate(IV)

Triphenylphosphine oxide