chloro(dicyclohexylphenylphosphine)gold(I)

Base Information

• Chemical Name: chloro(dicyclohexylphenylphosphine)gold(I)
• CAS No.: 134535-05-0
• Molecular Formula: C₁₈H₂₇AuClP
• Molecular Weight: 506.806
• Mol file: 134535-05-0.mol

Synonyms:Phosphine,dicyclohexylphenyl-, gold complex; Chloro(dicyclohexylphenylphosphine)gold

Chemical Property of chloro(dicyclohexylphenylphosphine)gold(I)

Chemical Property:

• Vapor Pressure: 7.38E-07mmHg at 25°C
• Boiling Point: 419.5°Cat760mmHg
• Flash Point: 207.5°C
• PSA: 13.59000
• Density: g/cm³
• LogP: 6.11010

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chloro(dicyclohexylphenylphosphine)gold(I)

There total 1 articles about chloro(dicyclohexylphenylphosphine)gold(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

chloroauric acid + dicyclohexylphenylphosphine (6476-37-5) → chloro(dicyclohexylphenylphosphine)gold(I) (134535-05-0)

Guidance literature:

With 2,2'thiodiethanol; In ethanol; dissolving 0.0027mmol of tetrachloroauric acid in 40ml EtOH, reducing with 2,2'thiodiethanol (0.038mol), 2h stirring (until becomming almost colorless); addg. of a stoichiometric amt. of Cy2PhP inside a glove bag (N2);; vacuum filtn.; elem. anal.;;

Reference yield:

chloro(dicyclohexylphenylphosphine)gold(I) (134535-05-0) + dicyclohexylphenylphosphine (6476-37-5) → chlorobis(dicyclohexylphenylphosphine)gold(I) (117412-16-5)

Guidance literature:

In ethanol; mixt. stirred under N2 for 25 min, solvent evapd., acetone added and ppt. filtered off; soln. in ethanol and slow evapn., elem. anal.;

Reference yield:

ammonium perchlorate (7790-98-9) + chloro(dicyclohexylphenylphosphine)gold(I) (134535-05-0) + dicyclohexylphenylphosphine (6476-37-5) → tris(dicyclohexylphenylphosphine)gold(I) perchlorate

Guidance literature:

In ethanol; byproducts: NH4Cl; addn. of NH4ClO4 and sixfold excess of ligand added to soln. of complex under N2 in a glove bag, stirred for 20 min; filtered, crystn., filtered (vac.); elem. anal.;

upstream raw materials:

dicyclohexylphenylphosphine

Downstream raw materials:

chlorobis(dicyclohexylphenylphosphine)gold(I)