1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

Base Information

Chemical Name:1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose
CAS No.:1318793-79-1
Molecular Formula:C₂₄H₃₂O₆
Molecular Weight:416.514
Hs Code.:

Synonyms:1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

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Chemical Property of 1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

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Technology Process of 1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

There total 10 articles about 1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1333071-88-7
2,3,4,6-tetra-O-acetyl-1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

: 1318793-79-1
1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

Guidance literature:: 2,3,4,6-tetra-O-acetyl-1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose; With methanol; sodium; at 20 ℃;

at 20 ℃; pH=7;
DOI:10.1002/cjoc.201190222

Reference yield:

: 1280217-75-5
C₁₈H₂₁BrO

: 1318793-79-1
1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 4 steps

1.1: n-butyllithium / tetrahydrofuran; ethanol; hexane; nitrogen / 0.5 h / -78 °C / Inert atmosphere; liquid N₂

1.2: 0.5 h / -78 °C / Inert atmosphere; liquid N₂

1.3: 20 °C / Inert atmosphere; liquid N₂

2.1: triethylsilane; boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C

3.1: sodium acetate; acetic acid / 5.5 h / 0 °C / Reflux

4.1: methanol; sodium / 20 °C

4.2: strongly acidic resin (H⁺ form) / 20 °C / pH 7

With methanol; triethylsilane; n-butyllithium; boron trifluoride diethyl etherate; sodium acetate; sodium; acetic acid; In tetrahydrofuran; ethanol; hexane; dichloromethane; nitrogen;
DOI:10.1002/cjoc.201190222

Reference yield:

: 1262035-46-0
1-(5-bromo-2-methylphenyl)-1-methylethanol

: 1318793-79-1
1-deoxy-1-{3-[1-(4-ethoxyphenyl)-1-methylethyl]-4-methylphenyl}-β-D-glucopyranose

Guidance literature:: Multi-step reaction with 5 steps

1.1: aluminum (III) chloride / dichloromethane / 3.25 h / 0 - 20 °C

2.1: n-butyllithium / tetrahydrofuran; ethanol; hexane; nitrogen / 0.5 h / -78 °C / Inert atmosphere; liquid N₂

2.2: 0.5 h / -78 °C / Inert atmosphere; liquid N₂

2.3: 20 °C / Inert atmosphere; liquid N₂

3.1: triethylsilane; boron trifluoride diethyl etherate / dichloromethane / 0 - 20 °C

4.1: sodium acetate; acetic acid / 5.5 h / 0 °C / Reflux

5.1: methanol; sodium / 20 °C

5.2: strongly acidic resin (H⁺ form) / 20 °C / pH 7

With methanol; triethylsilane; aluminum (III) chloride; n-butyllithium; boron trifluoride diethyl etherate; sodium acetate; sodium; acetic acid; In tetrahydrofuran; ethanol; hexane; dichloromethane; nitrogen; 1.1: Friedel Crafts alkylation;
DOI:10.1002/cjoc.201190222