(+)-pinocamphyl chloride

Base Information

• Chemical Name: (+)-pinocamphyl chloride
• CAS No.: 185378-26-1
• Molecular Formula: C₁₀H₁₇Cl
• Molecular Weight: 172.698
• Mol file: 185378-26-1.mol

Synonyms:(+)-pinocamphyl chloride

Chemical Property of (+)-pinocamphyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+)-pinocamphyl chloride

There total 1 articles about (+)-pinocamphyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

(-)-isopinocampheol (1196-00-5) → (+)-α-pinene (7785-70-8,25766-18-1) + (+)-pinocamphyl chloride (185378-26-1)

Guidance literature:

With tetrachloromethane; triphenylphosphine; for 16h; Heating;

DOI:10.1021/jo961708s

Reference yield:

(+)-pinocamphyl chloride (185378-26-1) → (1R,2R,3R,5S)-3-(2-Methoxy-1-methyl-2-phenyl-ethylselanyl)-2,6,6-trimethyl-bicyclo[3.1.1]heptane

Guidance literature:

Multi-step reaction with 2 steps

1.1: 32 percent / N₂H₄*H₂O; Se; NaOH / dimethylformamide / 2 h / 100 °C

2.1: Br₂ / CH₂Cl₂; CCl₄ / 0.25 h / -78 °C

2.2: silver triflate / CH₂Cl₂; CCl₄ / 0.25 h / -78 °C

2.3: 48 percent / CH₂Cl₂; CCl₄ / -78 °C

With sodium hydroxide; selenium; bromine; hydrazine hydrate; In tetrachloromethane; dichloromethane; N,N-dimethyl-formamide;

DOI:10.1002/ejoc.200600044

upstream raw materials:

(-)-isopinocampheol

Refernces