benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

Base Information

Chemical Name:benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside
CAS No.:174356-42-4
Molecular Formula:C₆₅H₅₆Cl₄N₂O₁₄
Molecular Weight:1230.98
Hs Code.:

benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

Synonyms:benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

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Chemical Property of benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

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Technology Process of benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

There total 10 articles about benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 174356-29-7
pent-4-enyl 3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside

: 174356-30-0
benzyl 3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachloro-phthalimido-β-D-glucopyranoside

: 174356-42-4
benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

Guidance literature:: With N-iodo-succinimide; triethylsilyl trifluoromethyl sulfonate; In dichloromethane;
DOI:10.1021/jo951943v

Reference yield:

: 1125-88-8
benzaldehyde dimethyl acetal

: 174356-42-4
benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 4 steps

1: p-TsOH / acetonitrile / 10 h / Heating

2: 93 percent / pyridine / 3 h

3: 87 percent / NaCNBH₃, HCl gas, mol. sieves 3A / tetrahydrofuran; diethyl ether

4: 70 percent / N-iodosuccinimide, triethylsilyl triflate / CH₂Cl₂ / 0.42 h / Ambient temperature

With pyridine; hydrogenchloride; N-iodo-succinimide; 3 A molecular sieve; triethylsilyl trifluoromethyl sulfonate; sodium cyanoborohydride; toluene-4-sulfonic acid; In tetrahydrofuran; diethyl ether; dichloromethane; acetonitrile;
DOI:10.1016/S0968-0896(96)00173-3

Reference yield:

: 100-39-0
benzyl bromide

: 174356-42-4
benzyl (3,4,6-tri-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl)-(1->4)-3-O-acetyl-6-O-benzyl-2-deoxy-2-tetrachlorophthalimido-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / Bu₄NI, NaH / dimethylformamide / 3 h / 0 - 20 °C

2: 70 percent / N-iodosuccinimide, triethylsilyl triflate / CH₂Cl₂ / 0.42 h / Ambient temperature

With N-iodo-succinimide; triethylsilyl trifluoromethyl sulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; In dichloromethane; N,N-dimethyl-formamide;
DOI:10.1016/S0968-0896(96)00173-3