6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

Base Information

Chemical Name:6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate
CAS No.:1536481-24-9
Molecular Formula:C₁₉H₂₆O₆S
Molecular Weight:382.478
Hs Code.:

Synonyms:6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

Suppliers and Price of 6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

There total 1 articles about 6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 7633-32-1
tert-butyl glyoxylate

: 105126-90-7
(4-methoxyphenylthio)acetaldehyde

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 1536481-24-9
6-tert-butyl 1-ethyl (4S,5S,E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

: 6-tert-butyl 1-ethyl (E)-5-hydroxy-4-((4-methoxyphenyl)thio)hex-2-enedioate

Guidance literature:: tert-butyl glyoxylate; (4-methoxyphenylthio)acetaldehyde; With N-(4,5-dihydro-3H-4-aza-cyclohepta[2,1-a;3,4-a']dinaphthalen-2-yl)-C,C,C-trifluoro-methanesulfonamide; In 1-methyl-pyrrolidin-2-one; at -20 ℃; for 12h;

ethyl (triphenylphosphoranylidene)acetate; In chloroform; at 20 ℃; for 2h; Overall yield = 71 %; enantioselective reaction;
DOI:10.1021/ol4036837