(1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

Base Information

• Chemical Name: (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene
• CAS No.: 84109-51-3
• Molecular Formula: C₁₃H₁₄O₄
• Molecular Weight: 234.252

Synonyms:(1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

Chemical Property of (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

Chemical Property:

Purity/Quality:

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Technology Process of (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

There total 3 articles about (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C27H28O9S2 (84170-90-1) → (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene (84109-51-3)

Guidance literature:

With sodium methylate; In dichloromethane; for 24h; Yield given; Ambient temperature;

DOI:10.1021/ja00341a052

Reference yield:

benzaldehyde dimethyl acetal (1125-88-8) → (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene (84109-51-3)

Guidance literature:

Multi-step reaction with 3 steps

1: TsOH

2: 70 percent / pyridine

3: MeONa / CH₂Cl₂ / 24 h / Ambient temperature

With sodium methylate; toluene-4-sulfonic acid; In pyridine; dichloromethane;

DOI:10.1021/ja00341a052

Reference yield:

(2S,4aS,7R,8S,8aR)-2-Phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol (84170-89-8) → (1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene (84109-51-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 70 percent / pyridine

2: MeONa / CH₂Cl₂ / 24 h / Ambient temperature

With sodium methylate; In pyridine; dichloromethane;

DOI:10.1021/ja00341a052

upstream raw materials:

C₂₇H₂₈O₉S₂

benzaldehyde dimethyl acetal

(2S,4aS,7R,8S,8aR)-2-Phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

Downstream raw materials:

1-{(2S,3R,4R,5S)-3,4-Dihydroxy-5-[(2R,3R)-3-((1S,2S)-2-hydroxy-1-methyl-propyl)-oxiranylmethyl]-tetrahydro-pyran-2-yl}-propan-2-one

Toluene-4-sulfonic acid (3aR,4S,7S,7aR)-7-((E)-(4R,5S)-5-hydroxy-4-methyl-hex-2-enyl)-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran-4-ylmethyl ester

<(2S,3R,4R,5S)-5-<(2S,3S,4S,5S)-(2,3-epoxy-5-hydroxy-4-methylhexyl)>-3,4-dihydroxytetrahydropyran-2-yl>acetone

(2S,4aS,7S,8R,8aR)-7-[(E)-(4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

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