(2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Base Information

Chemical Name:(2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol
CAS No.:84109-57-9
Molecular Formula:C₂₆H₄₂O₅Si
Molecular Weight:462.702
Hs Code.:

Synonyms:(2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

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Chemical Property of (2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

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Technology Process of (2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

There total 14 articles about (2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

: 84109-51-3
(1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

: C₁₃H₂₇ClMgOSi

: 84109-57-9
(2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

: 84109-57-9
(2S,4aS,7S,8R,8aR)-7-[(E)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Guidance literature:: With copper(l) iodide; THF, -30 deg C, 10 min;
DOI:10.1021/ja00341a052

Reference yield: 43.0%

: 84109-51-3
(1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

: C₁₃H₂₇ClMgOSi

: 84109-57-9
(2S,4aS,7S,8R,8aR)-7-[(Z)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

: 84109-57-9
(2S,4aS,7S,8R,8aR)-7-[(E)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Guidance literature:: With copper(l) iodide; THF, -30 deg C, 10 min;
DOI:10.1021/ja00341a052

Reference yield:

: 84109-51-3
(1aR,3aS,6S,7aS,7bR)-6-Phenyl-hexahydro-1,3,5,7-tetraoxa-cyclopropa[a]naphthalene

: C₁₃H₂₇ClMgOSi

: 84109-57-9
(2S,4aS,7S,8R,8aR)-7-[(E)-(4S,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

: 84109-57-9
(2S,4aS,7S,8R,8aR)-7-[(E)-(4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-hex-2-enyl]-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-ol

Guidance literature:: With copper(l) iodide; In tetrahydrofuran; at -30 ℃; for 0.166667h; Title compound not separated from byproducts;
DOI:10.1021/ja00341a052