(Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

Base Information

Chemical Name:(Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene
CAS No.:849411-80-9
Molecular Formula:C₃₄H₅₆O₂Si₂
Molecular Weight:552.988
Hs Code.:

Synonyms:(Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

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Chemical Property of (Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

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Technology Process of (Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

There total 6 articles about (Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 144693-95-8
tert-butyldipheny((2-methylpent-4-en-1-yl)oxy)silane

: 849411-77-4
6-(tert-butyldimethylsilanyloxy)-2-iodohex-2-ene

: 849411-80-9
(Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

Guidance literature:: tert-butyldipheny((2-methylpent-4-en-1-yl)oxy)silane; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 0 ℃; for 2h;

6-(tert-butyldimethylsilanyloxy)-2-iodohex-2-ene; With potassium phosphate; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; 1,4-dioxane; at 85 ℃; for 5h;
DOI:10.1021/jo048115z

Reference yield:

: 1575-74-2
(+-)-2-methyl-pent-4-enoic acid

: 849411-80-9
(Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

Guidance literature:: Multi-step reaction with 3 steps

1.1: LiAlH₄ / tetrahydrofuran / 16 h / 20 °C

2.1: 91 percent / imidazole / dimethylformamide / 12 h / 20 °C

3.1: 9-BBN-H / tetrahydrofuran / 2 h / 0 °C

3.2: 82 percent / K₃PO₄ / Pd(PPh₃)4 / tetrahydrofuran; dioxane / 5 h / 85 °C

With 1H-imidazole; lithium aluminium tetrahydride; 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; N,N-dimethyl-formamide; 3.2: Suzuki-Miyaura coupling;
DOI:10.1021/jo048115z

Reference yield:

: 5673-98-3
2-methylpent-4-en-1-ol

: 849411-80-9
(Z)-1-(tert-butyldimethylsilanyloxy)-10-(tert-butyldiphenylsilanyloxy)-5,9-dimethyldec-4-ene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 91 percent / imidazole / dimethylformamide / 12 h / 20 °C

2.1: 9-BBN-H / tetrahydrofuran / 2 h / 0 °C

2.2: 82 percent / K₃PO₄ / Pd(PPh₃)4 / tetrahydrofuran; dioxane / 5 h / 85 °C

With 1H-imidazole; 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; N,N-dimethyl-formamide; 2.2: Suzuki-Miyaura coupling;
DOI:10.1021/jo048115z