4'-(BrC₆H₂(CH₂NMe₂)2-2,6)-trimethyltin

Base Information

• Chemical Name: 4'-(BrC₆H₂(CH₂NMe₂)2-2,6)-trimethyltin
• CAS No.: 881014-03-5
• Molecular Formula: C₁₅H₂₇BrN₂Sn
• Molecular Weight: 434.007
• Mol file: 881014-03-5.mol

Synonyms:4'-(BrC₆H₂(CH₂NMe₂)2-2,6)-trimethyltin

Chemical Property of 4'-(BrC₆H₂(CH₂NMe₂)2-2,6)-trimethyltin

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of 4'-(BrC₆H₂(CH₂NMe₂)2-2,6)-trimethyltin

There total 1 articles about 4'-(BrC₆H₂(CH₂NMe₂)2-2,6)-trimethyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

trimethyltin(IV)chloride (1066-45-1) + 1-bromo-4-iodo-2,6-bis[(dimethylamino)methyl]benzene (312304-54-4) → 4'-(BrC6H2(CH2NMe2)2-2,6)-trimethyltin (881014-03-5)

Guidance literature:

With t-BuLi; In diethyl ether; pentane; under N2 atm. soln. t-BuLi in pentane was added dropwise to soln. IC6H2(CH2NMe2)2Br in Et2O at -100°C, after 15 min soln. Me3SnCl in Et2Owas added, allowed to warm to room temp. and stirred overnight; water was added, 0.1 M NaOH was added, Et2O layer was separated, washed with brine, dried over MgSO4 and concd.; elem. anal.;

DOI:10.1021/ic051967c

upstream raw materials:

trimethyltin(IV)chloride

1-bromo-4-iodo-2,6-bis[(dimethylamino)methyl]benzene