dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

Base Information

Chemical Name:dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate
CAS No.:472993-94-5
Molecular Formula:C₁₉H₂₂O₅Se
Molecular Weight:409.341
Hs Code.:

Synonyms:dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

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Chemical Property of dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

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Technology Process of dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

There total 1 articles about dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 5707-04-0
Phenylselenyl chloride

: 106094-16-0
dimethyl 1-<2-carboxylato-2-propenyl>-1,2-dihydrobenzoate

: 472993-94-5
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

Guidance literature:: With silver trifluoroacetate; potassium carbonate; Yield given. Multistep reaction; 1) CH₂Cl₂, -78 deg C, 15 min, 2) CH₂Cl₂, RT, 5 h;
DOI:10.1021/ja00238a029

Reference yield: 95.0%

: 472993-94-5
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

: 472994-08-4
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleninyl)-4-hydroxycyclohex-5-ene-1-carboxylate

Guidance literature:: With dihydrogen peroxide; In tetrahydrofuran; dichloromethane; at 5 ℃; for 2.5h;
DOI:10.1021/ja00238a029

Reference yield:

: 472993-94-5
dimethyl 1-<2-carboxylato-2-propenyl>-3-(phenylseleno)-4-hydroxycyclohex-5-ene-1-carboxylate

: 106094-25-1
dimethyl 4-epi-carbaprephenate

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / 30percent H₂O₂ / CH₂Cl₂; tetrahydrofuran / 2.5 h / 5 °C

2: 46 percent / Et₂NH / CH₂Cl₂; hexane / 2 h / Heating

With dihydrogen peroxide; diethylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja00238a029