bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

Base Information

Chemical Name:bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate
CAS No.:334698-26-9
Molecular Formula:C₅₆H₄₆P₂Rh*F₆P
Molecular Weight:1028.8
Hs Code.:

Synonyms:bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

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Technology Process of bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

There total 1 articles about bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 17084-13-8
potassium hexafluorophosphate

: 334830-79-4
rac-[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]

: chloro(1,5-cyclooctadiene)rhodium(I) dimer

: 334698-26-9
bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

Guidance literature:: In acetonitrile; mixed, refluxed for 20 min; not isolated, detected by NMRevapd., dissolved (CH2Cl2), filtered, crystd.(leyered toluene);
DOI:10.1039/b002906h

Reference yield: 95.0%

: 334698-26-9
bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

: 334698-24-7
[rac(5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene)]Rh[(C₆H₅)2C₄H₄P(C₆H₅)2]

Guidance literature:: With potassium tert-butoxide; In tetrahydrofuran; Rh complex as suspn. mixed with potassium tert-butoxide in THF; pptd.(hexane), elem. anal.;
DOI:10.1039/b002906h

Reference yield: 72.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 334698-26-9
bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I) hexafluorophosphate

: 7440-09-7
potassium

: 334785-22-7
bis[rac[5-diphenylphosphanyl-10-methyl-5H-dibenzo[a,d]cycloheptene]]rhodium(I-) K(THF)6

Guidance literature:: In tetrahydrofuran; alcali metal added to suspn. of Rh complex in THF, stirred; filtered, crystd.(layered hexane);
DOI:10.1039/b002906h