CHROMIC POTASSIUM OXALATE

Base Information

• Chemical Name: CHROMIC POTASSIUM OXALATE
• CAS No.: 14217-01-7
• Molecular Formula: C₆CrO₁₂*3K
• Molecular Weight: 433.35
• Mol file: 14217-01-7.mol

Synonyms:Chromate(3-),tris(oxalato)-, tripotassium (8CI);Chromate(3-), tris[ethanedioato(2-)-O,O']-,tripotassium, (OC-6-11)-;Chromate(3-), tris[ethanedioato(2-)-kO1,kO2]-, tripotassium, (OC-6-11)- (9CI);Potassiumoxalatochromate(III) (K3[Cr(C2O4)3]) (6CI);Chromic potassium oxalate;NSC43606;NSC 43989;Potassium trioxalatochromate (III);Potassiumtrioxalatochromate(3-);Potassium tris(oxalato)chromate(3-);Tripotassiumtrioxalatochromate;Tripotassium trioxalatochromate(3-);Tripotassiumtris(oxalato)chromate;Tripotassium tris(oxalato)chromate(3-);Tripotassiumtris(oxalato)chromate(III);

Chemical Property of CHROMIC POTASSIUM OXALATE

Chemical Property:

• Vapor Pressure: 2.51E-06mmHg at 25°C
• Boiling Point: 365.1°Cat760mmHg
• Flash Point: 188.8°C
• PSA: 199.29000
• Density: g/cm³
• LogP: -6.76860

Purity/Quality:

99% ^*data from raw suppliers

CHROMIC POTASSIUM OXALATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CHROMIC POTASSIUM OXALATE

There total 3 articles about CHROMIC POTASSIUM OXALATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium tris(oxalato)chromate(III) → K3(Δ-[Cr(oxalato)3]) (25978-34-1,14217-01-7)

Guidance literature:

With Λ-(+)-cis-Cr(ethylenediamine)2(N3)2(1+); In 1,4-dioxane; water; Cr-complexes mixed in water, dioxane added, kept overnight in the dark;equil. react.; passed through cation-exchange column cooled with ice water; detected by CD spectra;

DOI:10.1021/ic50218a021

Reference yield:

potassium tris(oxalato)chromate(III) → (+)ΛK3[Cr(oxalate)3] (14217-01-7)

Guidance literature:

With Λ-(-)-cis-[Co(ethylenediamine)2(N3)2](1+); In 1,4-dioxane; water; Cr-complex mixed with Co-complex in water, dioxane added, kept overnight in the dark; equil. react.; passed through cation-exchange column cooled with ice water; detected by CD spectra;

DOI:10.1021/ic50218a021

Reference yield:

potassium tris(oxalato)chromate(III) + Λ(-)-tris(ethylenediamine)rhodium(III) chloride trihydrate (15004-86-1) → K3(Δ-[Cr(oxalato)3]) (25978-34-1,14217-01-7) + Λ(-)-[Rh(ethylenediamine)3]Λ[Cr(oxalate)3] * x H2O

Guidance literature:

In water; pptn. on mixing; collection (filtration or centrifugation), washing (water, EtOH); dryingin air; elem. anal.;

DOI:10.1039/DT9760000594

upstream raw materials:

Λ(-)-tris(ethylenediamine)rhodium(III) chloride trihydrate

Refernces

• 1、 Miyoshi, Katsuhiko,Matsumoto, Yuuko,Yoneda, Hayami. "Application of the Pfeiffer effect to the assignment of absolute configurations to octahedral metal complexes of the type cis-[M(diamine)2(X)(Y)]n+ and related complexes". . p. 1057 - 1062. Retrieved 2008/10/08.