cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

Base Information

Chemical Name:cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene
CAS No.:125113-18-0
Molecular Formula:C₂₈H₃₂O₄SSi
Molecular Weight:492.711
Hs Code.:

Synonyms:cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

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Chemical Property of cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

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Technology Process of cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

There total 5 articles about cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 125113-17-9
cis-1,4-dihydroxy-2-phenylsulfonylcyclohex-2-ene

: 58479-61-1
tert-butylchlorodiphenylsilane

: 125113-18-0
cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

Guidance literature:: With silver nitrate; In tetrahydrofuran; for 0.0166667h;

Reference yield:

: 107657-92-1
trans-4-hydroxy-3-phenylsulfenylcyclohex-1-ene

: 125113-18-0
cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

Guidance literature:: Multi-step reaction with 3 steps

1: 91 percent / MCPBA / CH₂Cl₂ / 1.) 0 deg C, 15 min, 2.) room temperature, 17 h

2: 76 percent / DBU / tetrahydrofuran / 0.5 h

3: 86 percent / AgNO₃ / tetrahydrofuran / 0.02 h

With silver nitrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;

Reference yield:

: 1165952-91-9
cyclohexa-1,3-diene

: 125113-18-0
cis-4-(t-butyldiphenylsilyloxy)-1-hydroxy-2-phenylsulfonylcyclohex-2-ene

Guidance literature:: Multi-step reaction with 4 steps

1: 1.) MeCO₃H, 2.) Et₃N / 1.) toluene, room temperature, 3 h, 2.) room temperature, 2 h

2: 91 percent / MCPBA / CH₂Cl₂ / 1.) 0 deg C, 15 min, 2.) room temperature, 17 h

3: 76 percent / DBU / tetrahydrofuran / 0.5 h

4: 86 percent / AgNO₃ / tetrahydrofuran / 0.02 h

With peracetic acid; silver nitrate; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;