C₁₂H₁₇BrO₂

Base Information

• Chemical Name: C₁₂H₁₇BrO₂
• CAS No.: 914225-37-9
• Molecular Formula: C₁₂H₁₇BrO₂
• Molecular Weight: 273.17
• Mol file: 914225-37-9.mol

Synonyms:C₁₂H₁₇BrO₂

Chemical Property of C₁₂H₁₇BrO₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₂H₁₇BrO₂

There total 2 articles about C₁₂H₁₇BrO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-bromo-4-tert-butylphenol (2198-66-5) + chloromethyl methyl ether (107-30-2) → C12H17BrO2 (914225-37-9)

Guidance literature:

2-bromo-4-tert-butylphenol; With potassium hydroxide; In acetonitrile; at 20 ℃; for 4h; Inert atmosphere;

chloromethyl methyl ether; In acetonitrile; for 8h; Inert atmosphere;

Reference yield:

bromethyl methyl ether (13057-17-5) + 2-bromo-4-tert-butylphenol (2198-66-5) → C12H17BrO2 (914225-37-9)

Guidance literature:

With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃; for 2h;

DOI:10.1002/adsc.201800611

Reference yield: 65.0%

9,10-Dibromoanthracene (523-27-3) + C12H17BrO2 (914225-37-9) → C27H28O2

Guidance literature:

C₁₂H₁₇BrO₂; With tert.-butyl lithium; In tetrahydrofuran; for 0.5h; Inert atmosphere; Glovebox; Schlenk technique;

With zinc(II) chloride; In tetrahydrofuran; at 20 ℃; for 1h; Inert atmosphere; Glovebox; Schlenk technique;

9,10-Dibromoanthracene; With tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 70 ℃; for 36h; Inert atmosphere; Glovebox; Schlenk technique;

DOI:10.1021/acs.organomet.7b00015

upstream raw materials:

bromethyl methyl ether

2-bromo-4-tert-butylphenol

chloromethyl methyl ether

Downstream raw materials:

C₄₄H₅₇NO₂

(CH(CH₃)2)2C₆H₃NCHC(CH₃)3OHC₆H₂C₆(CH₃)4C₆H₃(C(CH₃)3)2

methoxymethyl ether of p-tert-butylphenol

C₅₆H₇₂N₂O₂