Technology Process of 1,2-(C6H5CH2)2-1,2-C2B10H10
There total 4 articles about 1,2-(C6H5CH2)2-1,2-C2B10H10 which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
n-BuLi; H2O;
In
diethyl ether; hexane; toluene;
N2-atmosphere; stirring (0°C to room temp., room temp., 30 min), C6H5CH2Br addn. (0°C), refluxing (overnight), H2O addn.; extg. (Et2O), drying (MgSO4), evapn., pptn. on hexane addn.;
- Guidance literature:
-
With
n-butyllithium;
In
1,2-dimethoxyethane; diethyl ether;
N2-atmosphere; stirring suspn. of borane and BuLi (0°C, 0.5 h, 25°C, 0,5 h), cooling to 0°C, slow addn. of BrCH2Ph (0.5 h), stirring (0°C, 0.5 h), stirring (room temp, 0.5 h), evapn. (vac.); org. layer drying (MgSO4), evapn.; (11)B NMR spectroscopy;
DOI:10.1021/ic00118a041
- Guidance literature:
-
With
n-BuLi;
In
diethyl ether;
under N2 atm. to soln. o-carborane in Et2O at -78°C n-BuLi was added and stirred for 50 min, benzyl chloride was added and stirred for 3 h, react. mixt. was warmed to 22°C and stirred for 18 h; react. mixt. was washed with water, dried over Na2SO4 and evapd. in vacuo, chromy. on silica using an automated purification system (2-20 % CH2Cl2 in hexane);
DOI:10.1021/ic0617543
