(2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

Base Information

Chemical Name:(2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate
CAS No.:122172-23-0
Molecular Formula:C₃₀H₃₂O₄
Molecular Weight:456.582
Hs Code.:

Synonyms:(2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

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Chemical Property of (2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

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Technology Process of (2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

There total 5 articles about (2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

: 122172-22-9,29969-62-8
ethyl 2-(4-methoxyphenyl)-2-formyl acetate

: 86835-18-9
(4S)-3-exo-(1-naphthyl)-4,7,7-trimethylbicyclo[2.2.1]heptan-2-exo-ol

: 122172-23-0
(2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

Guidance literature:: With dmap; In toluene; for 18h; Heating;
DOI:10.1021/jo00277a017

Reference yield:

: 104-01-8
4-Methoxyphenylacetic acid

: 122172-23-0
(2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

Guidance literature:: Multi-step reaction with 3 steps

1: 87 percent / concd H₂SO₄ / 18 h / Heating

2: 88 percent / sodium metal, ethanol / diethyl ether / 1.) 0 deg C, 2 h, 2.) room temp., 14 h

3: 71 percent / 4-(dimethylamino)pyridine / toluene / 18 h / Heating

With dmap; ethanol; sulfuric acid; sodium; In diethyl ether; toluene;
DOI:10.1021/jo00277a017

Reference yield:

: 14062-18-1
ethyl p-methoxyphenylacetate

: 122172-23-0
(2R,3R)-1,7,7-trimethyl-2-(1-naphthyl)bicyclo<2.2.1>hept-3-yl 2-(4-methoxyphenyl)-3-oxopropanoate

Guidance literature:: Multi-step reaction with 2 steps

1: 88 percent / sodium metal, ethanol / diethyl ether / 1.) 0 deg C, 2 h, 2.) room temp., 14 h

2: 71 percent / 4-(dimethylamino)pyridine / toluene / 18 h / Heating

With dmap; ethanol; sodium; In diethyl ether; toluene;
DOI:10.1021/jo00277a017