5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

Base Information

Chemical Name:5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane
CAS No.:1429638-49-2
Molecular Formula:C₂₁H₃₆O₄Si
Molecular Weight:380.6
Hs Code.:

Synonyms:5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

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Chemical Property of 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

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Technology Process of 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

There total 3 articles about 5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 1429638-47-0
1-(benzyloxy)-2-((tert-butyldimethylsilyloxy)methyl)-3-methylbut-3-en-2-ol

: 150587-19-2
methoxymethoxy chloride

: 1429638-49-2
5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

Guidance literature:: With N-ethyl-N,N-diisopropylamine; sodium iodide; In 1,2-dichloro-ethane; at 85 ℃; for 120h; Inert atmosphere;
DOI:10.1021/ol4005799

Reference yield:

: 1429638-46-9
2-(((tert-butyldimethylsilyl)oxy)methyl)-3-methylbut-3-ene-1,2-diol

: 1429638-49-2
5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

Guidance literature:: Multi-step reaction with 2 steps

1.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / -40 °C / Inert atmosphere

1.2: -20 °C / 18 Torr / Inert atmosphere

2.1: N-ethyl-N,N-diisopropylamine; sodium iodide / 1,2-dichloro-ethane / 120 h / 85 °C / Inert atmosphere

With sodium hydride; N-ethyl-N,N-diisopropylamine; sodium iodide; In 1,2-dichloro-ethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/ol4005799

Reference yield:

: 158465-80-6
1-((tert-butyldimethylsilyl)oxy)-3-hydroxypropan-2-one

: 1429638-49-2
5-((benzyloxy)methyl)-8,8,9,9-tetramethyl-5-(prop-1-en-2-yl)-2,4,7-trioxa-8-siladecane

Guidance literature:: Multi-step reaction with 3 steps

1.1: tetrahydrofuran / 2 h / -78 - 20 °C / Inert atmosphere

2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 1 h / -40 °C / Inert atmosphere

2.2: -20 °C / 18 Torr / Inert atmosphere

3.1: N-ethyl-N,N-diisopropylamine; sodium iodide / 1,2-dichloro-ethane / 120 h / 85 °C / Inert atmosphere

With sodium hydride; N-ethyl-N,N-diisopropylamine; sodium iodide; In tetrahydrofuran; 1,2-dichloro-ethane; N,N-dimethyl-formamide; mineral oil;
DOI:10.1021/ol4005799