(1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

Base Information

Chemical Name:(1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)
CAS No.:131135-77-8
Molecular Formula:C₃₈H₃₄P₂PdSe₂
Molecular Weight:816.975
Hs Code.:

Synonyms:(1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

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Chemical Property of (1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

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Technology Process of (1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

There total 3 articles about (1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 19978-61-1
(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

: 1666-13-3
diphenyl diselenide

: 131135-77-8
(1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

Guidance literature:: With NaBH₄; In methanol; benzene; byproducts: NaCl; N2-atmosphere; treatment of Ph2Se2 with NaBH4 (in MeOH), addn. of suspn.of metal complex (in C6H6), stirring for 4 h; evapn., extn. into hot C6H6, filtration, vol. reduction, crystn. on cooling; elem. anal.;
DOI:10.1016/S0020-1693(98)00335-1

Reference yield: 71.0%

: 19978-61-1
(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

: 23974-72-3
sodium phenylselenide

: 131135-77-8
(1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

Guidance literature:: In ethanol; benzene; byproducts: NaCl; (N2); benzene suspension of complex was added to the ethanolic solution of Na-compound; stirring for 6 h; room temp.; filtration (celite); evapn. to dryness; dissolving in min. amount of CHCl3; mixing with diethyl ether ; sepn. of crystals by cooling overnight; washing (ether); drying in vac.; elem. anal.;

Reference yield:

: 63455-39-0
dimethyl[1,2-bis(diphenylphosphanyl)ethane]palladium

: 1666-13-3
diphenyl diselenide

: 131135-77-8
(1,2-bis(diphenylphosphino)ethane)bis(phenylselenolato)palladium(II)

: (methyl)(SeC₆H₅)[1,2-bis(diphenylphosphanyl)ethane]palladium

Guidance literature:: In tetrahydrofuran; tetrahydrofuran-d8; byproducts: CH3SeC6H5; to soln. of Pd(CH3)2(dppe) in THF/THF-d8 (4:1) added (C6H5Se)2 at -30°C under Ar, mixture transferred to NMR tube for 1 day; not isolated, identified by NMR;
DOI:10.1002/1099-0682(200211)2002:11<2868::AID-EJIC2868>3.0.CO;2-S