23974-72-3Relevant articles and documents
Synthesis and Structural Characterization of Copper(I) Phenylselenolate Complexes Stabilized by N,N′-Donor Ligands
Cabral, Bruno N.,Zawatski, Luana E.,Abram, Ulrich,Lang, Ernesto S.
, p. 739 - 743 (2015)
The reaction of sodium phenylselenolate and copper(I) chloride generates in situ a "CuSePh" species, which can be stabilized by N,N′-donor ligands such as bpy (2, 2′-bipyridine) or phen (1, 10-phenanthroline) in order to generate compounds with μ2/s
Synthesis, spectral characterization, and crystal structure of two polymorphs of o,o'-dichloro dibenzyl disulfide
Srivastava,Rastogi, Rupali,Rajaram,Butcher,Jasinski, Jerry P.
, p. 455 - 462 (2010)
2-Chlorophenyl methanethiol undergoes air oxidation catalyzed by different selenides and yields the corresponding disulfide 1 in two polymorphic forms, 1a and 1b. In the molecular structures of the two new polymorphs of o,o-dichloro dibenzyl disulfide, th
REACTION OF PERFLUOROALKYLETHYLENS WITH NUCLEOPHILES
Feiring, Andrew E.,Hovey, Michael C.,Arthur, Samuel D.
, p. 125 - 132 (1984)
Perfluoroalkylethylenes react with some carbon-, oxygen-, sulfur-, selenium-, nitrogen-, and phosphorus-based nucleophiles by formal SN2' displacement of fluoride ion.
1-(3-Chlorophenyl)-4-(3-phenylseleno propyl) piperazine (L); synthesis, spectroscopic characterization, DFT studies, antimicrobial evaluation and its reactivity toward group 12 metal chlorides
Bhat, Muzzaffar A.,Lone, Shabir H.,Srivastava, Sanjay K.
, p. 2800 - 2813 (2018)
C6H5Se?Na+ (generated in situ by NaBH4 reduction of (C6H5Se)2) on reaction with ClC3H6C4H8N2ClC6Hsub
(η6-Benzene)Ru(II) half-sandwich complexes of pyrazolated chalcogenoethers for catalytic activation of aldehydes to amides transformation
Sharma, Kamal Nayan,Ali, Munsaf,Srivastava, Avinash Kumar,Joshi, Raj Kumar
, p. 69 - 77 (2018/11/10)
The reaction of [(η6-C6H6)RuCl(μ-Cl)]2 with chalcogenoether substituted 1H-pyrazole ligands (L1-L3) in methanol have yielded three novel Ru(II) half-sandwich complexes [(η6-C6H6)RuCl(L)]PF6 (1–3) in high yield under the ambient reaction conditions. The NMR, MS and FT-IR analytical techniques were used to identify their structures. The molecular structures of the complexes 2 and 3 were established with X-ray crystallographic analysis and revealed a pseudo-octahedral half sandwich piano-stool geometry around ruthenium in each complex. Complexes 1–3 are thermally robust and were found to be insensitive towards the air and moisture. All the complexes were found to be catalytically active and produced the excellent yields of amides (up to 95%) from corresponding aldehydes. In contrast to the previous reported catalytic systems for aldehyde to amide transformation, the present complexes 1–3 are very efficient and have several advantages in terms of low catalyst loading, reaction time, temperature and wide applicability for various substituted aldehydes. Owing to the stronger σ-donor coordination properties of selenium containing ligands, the complex 2 was found to be more efficient as compare to the sulphur and tellurium analogues.
Synthesis, characterization and biological evaluation of new manganese metal carbonyl compounds that contain sulfur and selenium ligands as a promising new class of CORMs
Amorim, André L.,Peterle, Marcos M.,Guerreiro, Ana,Coimbra, Daniel F.,Heying, Renata S.,Caramori, Giovani F.,Braga, Antonio L.,Bortoluzzi, Adailton J.,Neves, Ademir,Bernardes, Gon?alo J. L.,Peralta, Rosely A.
, p. 5574 - 5584 (2019/05/10)
Three new manganese carbonyl compounds with heavy atom donors were synthesized and their potential use as photoCORMS was evaluated. Interestingly, all compounds had an elusive binding mode, in which the ligands adopted a κ2-X coordination (wher
