[3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate

Base Information

• Chemical Name: [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate
• CAS No.: 54423-54-0
• Molecular Formula: C41H39NO9
• Molecular Weight: 689.762
• Mol file: 54423-54-0.mol

Synonyms:[3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate;2,3,4,6-Tetra-O-benzyl-D-glucose-1-p-nitrobenzoate

Chemical Property of [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate

Chemical Property:

• Vapor Pressure: 3.53E-25mmHg at 25°C
• Boiling Point: 793.7 °C at 760 mmHg
• Flash Point: 258 °C
• PSA: 118.27000
• Density: 1.29 g/cm³
• LogP: 8.22500
• Storage Temp.: 2-8°C

Purity/Quality:

99% ^*data from raw suppliers

(3R,4S,5R,6R)-3,4,5-Tris(benzyloxy)-6-((benzyloxy)-methyl)tetrahydro-2H-pyran-2-yl 4-nitrobenzoate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate

There total 4 articles about [3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-yl] 4-nitrobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (4291-69-4,6386-24-9,6564-72-3,59531-24-7,69257-52-9,78184-89-1,78609-16-2,78609-17-3,78609-18-4,96553-53-6,104111-61-7,131347-08-5,4132-28-9) + 4-nitro-benzoic acid (62-23-7) → 2,3,4,6-Tetra-O-benzyl 1-O-p-nitrobenzoyl D-glucopyranoside (54423-54-0)

Guidance literature:

With di-isopropyl azodicarboxylate; 1,2-bis-(diphenylphosphino)ethane; In tetrahydrofuran;

DOI:10.1016/S0040-4039(98)01702-X

Reference yield:

2,3,4,6-tetra-O-benzyl-D-glucopyranose (6564-72-3) + 4-nitro-benzoyl chloride (122-04-3) → 2,3,4,6-Tetra-O-benzyl 1-O-p-nitrobenzoyl D-glucopyranoside (54423-54-0)

Guidance literature:

With pyridine; In ethanol;

Reference yield:

→ 1-<4-Nitro-benzoyl>-2.3.4.6-tetra-O-benzyl-glucopyranose (4196-36-5,53081-28-0,53081-29-1,54423-54-0,61375-73-3,61375-74-4,63087-91-2,67773-45-9)

Guidance literature:

Tetrabenzylglykose/CH2Cl2, 4-Nitro-benzoylchlorid ;

upstream raw materials:

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

4-nitro-benzoyl chloride

4-nitro-benzoic acid

2,3,4,6-tetra-O-benzyl-D-glucopyranose

Downstream raw materials:

(2R,3R,4R,5S,6R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-((Z)-2-iodo-vinyl)-tetrahydro-pyran

2,3,4,6-tetra-O-benzyl-α/β-D-glucopyranosyl bromide

2,3,4,6-tetra-O-benzyl-α-D-glucopyranosyl bromide

1-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranos-1-yl)-2-propene