(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

Base Information

Chemical Name:(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane
CAS No.:1270304-76-1
Molecular Formula:C₁₈H₃₁BO₂Si
Molecular Weight:318.339
Hs Code.:

Synonyms:(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

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Chemical Property of (R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

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Technology Process of (R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

There total 1 articles about (R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 959685-40-6
N,N-diisopropyl-carbamic acid isobutyl ester

: 185990-03-8
dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane

: 1270304-76-1
(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

Guidance literature:: N,N-diisopropyl-carbamic acid isobutyl ester; With sec.-butyllithium; (-)-sparteine; In diethyl ether; hexane; cyclohexane; at -78 ℃; for 5h; Inert atmosphere;

dimethylphenyl(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)silane; In diethyl ether; hexane; cyclohexane; at -78 - 23 ℃; Inert atmosphere;
DOI:10.1021/ol200177f

Reference yield: 80.0%

: 590-15-8
trans-2-propenyl bromide

: 1270304-76-1
(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

: 1270304-80-7
(S,Z)-dimethyl(2-methylhex-4-en-3-yl)(phenyl)silane

Guidance literature:: trans-2-propenyl bromide; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.5h; Inert atmosphere;

(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane; In tetrahydrofuran; pentane; at -78 - -45 ℃; for 2h; Inert atmosphere;

With iodine; In tetrahydrofuran; methanol; pentane; at -78 - 0 ℃; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ol200177f

Reference yield: 80.0%

: 590-13-6
(Z)-1-propenyl bromide

: 1270304-76-1
(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane

: 1270304-81-8
(S,E)-dimethyl(2-methylhex-4-en-3-yl)(phenyl)silane

Guidance literature:: (Z)-1-propenyl bromide; With tert.-butyl lithium; In tetrahydrofuran; pentane; at -78 ℃; for 0.5h; Inert atmosphere;

(R)-dimethyl(2-methyl-1-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)propyl)(phenyl)silane; In tetrahydrofuran; pentane; at -78 - -45 ℃; for 2h; Inert atmosphere;

With iodine; In tetrahydrofuran; methanol; pentane; at -78 - 0 ℃; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ol200177f