meso-tetra(m-methoxyphenyl)porphyrin

Base Information

• Chemical Name: meso-tetra(m-methoxyphenyl)porphyrin
• CAS No.: 29114-93-0
• Molecular Formula: C₄₈H₃₈N₄O₄
• Molecular Weight: 734.854
• Mol file: 29114-93-0.mol

Synonyms:meso-tetra(m-methoxyphenyl)porphyrin

Chemical Property of meso-tetra(m-methoxyphenyl)porphyrin

Chemical Property:

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of meso-tetra(m-methoxyphenyl)porphyrin

There total 13 articles about meso-tetra(m-methoxyphenyl)porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

meso-5,10,15,20-tetra(3-hydroxyphenyl)porphine (22112-79-4) + methyl iodide (74-88-4) → meso-tetra(m-methoxyphenyl)porphyrin (29114-93-0)

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In methanol; N,N-dimethyl-formamide; at 20 ℃; for 0.0166667h;

DOI:10.1142/S1088424615500728

Reference yield: 23.0%

meso-5,10,15,20-tetra(3-hydroxyphenyl)porphine (22112-79-4) + methyl iodide (74-88-4) → meso-tetra(m-methoxyphenyl)porphyrin (29114-93-0) + 5,10-bis(3-hydroxyphenyl)-15,20-bis(3-methoxyphenyl)porphyrin + 5-(3-hydroxyphenyl)-10,15,20-tris(3-methoxyphenyl)porphyrin

Guidance literature:

With tetra(n-butyl)ammonium hydroxide; In methanol; N,N-dimethyl-formamide; at 20 ℃; for 0.0166667h;

DOI:10.1142/S1088424615500728

Reference yield: 10.0%

pyrrole (109-97-7,30604-81-0) + 4-fluorobenzaldehyde (459-57-4) + 3-methoxy-benzaldehyde (591-31-1) → meso-tetra(m-methoxyphenyl)porphyrin (29114-93-0) + 5-(4-fluorophenyl)-10,15,20-tris(3-methoxyphenyl)porphyrin

Guidance literature:

pyrrole; 4-fluorobenzaldehyde; 3-methoxy-benzaldehyde; With trifluoroacetic acid; In dichloromethane; at 20 ℃; for 0.666667h;

With air; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; at 20 ℃; for 1h;

DOI:10.1002/jlcr.992

upstream raw materials:

methyl bromide

meso-5,10,15,20-tetra(3-hydroxyphenyl)porphine

pyrrole

4-nitrobenzaldehdye

Downstream raw materials:

5-(3-methoxy-6-nitrophenyl)-10,15,20-tris(3-methoxyphenyl)porphyrin