N,N-bis(diisopropylphosphino)-3,5-dimethylaniline

Base Information

• Chemical Name: N,N-bis(diisopropylphosphino)-3,5-dimethylaniline
• CAS No.: 1356198-97-4
• Molecular Formula: C₁₄H₂₄NP
• Molecular Weight: 237.325
• Mol file: 1356198-97-4.mol

Synonyms:N,N-bis(diisopropylphosphino)-3,5-dimethylaniline

Chemical Property of N,N-bis(diisopropylphosphino)-3,5-dimethylaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-bis(diisopropylphosphino)-3,5-dimethylaniline

There total 1 articles about N,N-bis(diisopropylphosphino)-3,5-dimethylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

Chlorodiisopropylphosphane (40244-90-4) + 3,5-dimethylaminoaniline (108-69-0) → N,N-bis(diisopropylphosphino)-3,5-dimethylaniline (1356198-97-4)

Guidance literature:

With triethylamine; In pentane; at 20 ℃; for 15h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c3dt52133h

Reference yield: 92.0%

bis(tetrahydrofuran)tris(trimethylsilylmethyl)yttrium(III) + N,N-bis(diisopropylphosphino)-3,5-dimethylaniline (1356198-97-4) → (P(CH(CH3)2)2NC6H3(CH3)2)Y(CH2Si(CH3)3)2(C4H8O) (1356199-01-3) + (P(CH(CH3)2)2NC6H3(CH3)2)2(CH2Si(CH3)3)Y(C4H8O) (1356199-02-4) + [(N-bis(diisopropylphosphino)-3,5-dimethylanilinato)3Y(THF)] (1356199-00-2)

Guidance literature:

In hexane; byproducts: Si(CH3)4; (N2, Schlenk) a soln. of aniline-compound in hexanes was added dropwise to a soln. of Y-complex in hexanes at room temp., stirring for 24 h; ppt. was washed with hexanes (2x), dried in vac.; elem. anal.;

DOI:10.1039/c1dt11501d

Reference yield: 84.0%

vanadium(lll) chloride THF complex + N,N-bis(diisopropylphosphino)-3,5-dimethylaniline (1356198-97-4) → V((3,5-dimethylphenyl)NPiPr2)3

Guidance literature:

N,N-bis(diisopropylphosphino)-3,5-dimethylaniline; With n-butyllithium; In diethyl ether; hexane; at -35 - 20 ℃; for 2h; Inert atmosphere;

vanadium(lll) chloride THF complex; In diethyl ether; hexane; at -35 - 20 ℃; for 12h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.6b01543

upstream raw materials:

Chlorodiisopropylphosphane

3,5-dimethylaminoaniline

Downstream raw materials:

(P(CH(CH₃)2)2NC₆H₃(CH₃)2)Y(CH₂Si(CH₃)3)2(C₄H₈O)

(P(CH(CH₃)2)2NC₆H₃(CH₃)2)2(CH₂Si(CH₃)3)Y(C₄H₈O)

[(N-bis(diisopropylphosphino)-3,5-dimethylanilinato)3Y(THF)]

[(N-bis(diisopropylphosphino)-3,5-dimethylanilinato)2(CH₂SiMe₃)Sc(THF)]