N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide

Base Information

• Chemical Name: N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide
• CAS No.: 1440762-38-8
• Molecular Formula: C₄₆H₄₅N₃O₅
• Molecular Weight: 719.88
• Mol file: 1440762-38-8.mol

Synonyms:N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property of N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide

There total 2 articles about N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

N,N’-bis(1-ethylpropyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide (1294450-29-5) + N-(2-bromo-4-tert-butylphenyl)acetamide (91801-97-7) → N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide (1440762-38-8)

Guidance literature:

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; potassium carbonate; In water; toluene; for 24h; Inert atmosphere; Reflux; Schlenk technique;

DOI:10.1021/ol401316q

Reference yield:

N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide) (110590-81-3) → N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide (1440762-38-8)

Guidance literature:

Multi-step reaction with 2 steps

1: tris(pentafluorophenyl)phosphine; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer / 1,4-dioxane / 24 h / 110 °C / Inert atmosphere

2: tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; potassium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane / toluene; water / 24 h / Inert atmosphere; Reflux; Schlenk technique

With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; potassium carbonate; tris(pentafluorophenyl)phosphine; In 1,4-dioxane; water; toluene; 2: |Suzuki-Miyaura Coupling;

DOI:10.1021/ol401316q

Reference yield:

N,N’-bis(1-ethylpropyl)-2-(4-tert-butylacetanilide-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide (1440762-38-8) → N,N’-bis(1-ethylpropyl)-6-tert-butyl-10,13,16-tris(2-cyclohexylethyl)benzo[b]peryleno[2,3,4-def][1,8]naphthyridin-1(2H)-one-11,12-dicarboxylic acid imide

Guidance literature:

Multi-step reaction with 2 steps

1: hydrogenchloride; water / methanol; water / 17 h / Reflux

2: carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II) / 1,3,5-trimethyl-benzene / 144 h / 170 °C / Inert atmosphere

With hydrogenchloride; carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II); water; In methanol; water; 1,3,5-trimethyl-benzene;

DOI:10.1021/ol401316q

upstream raw materials:

N,N’-bis(1-ethylpropyl)-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)perylene-3,4:9,10-tetracarboxylic acid bisimide

N-(2-bromo-4-tert-butylphenyl)acetamide

N,N'-bis(1-ethylpropyl)-3,4:9,10-perylenebis(dicarboximide)