bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)

Base Information

• Chemical Name: bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)
• CAS No.: 89506-21-8
• Molecular Formula: C₂₈H₂₇BrNO₂PPd
• Molecular Weight: 626.826
• Mol file: 89506-21-8.mol

Synonyms:bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)

Chemical Property of bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II)

There total 3 articles about bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

di-μ-bromobis(N-methyl-3,4-dimethoxybenzalimine-6,C,N)dipalladium(II) (89506-15-0) → bromo(N-methyl-3,4-dimethoxybenzalimine-6,C,N)triphenylphosphinepalladium(II) (89506-21-8)

Guidance literature:

With triphenylphosphine; In dichloromethane; byproducts: Pd; PPh3 and complex stirred at room temp. in CH2Cl2; filtered (celite), heated, pptd. (MeOH), filtered, washed (MeOH), dried; elem. anal.;

DOI:10.1016/0022-328X(84)80664-6

Reference yield:

N-methyl-3,4-dimethoxy-6-bromobenzalimine (89525-44-0) + bis(dibenzylideneacetone)-palladium(0) (32005-36-0) → [(C6H2(OCH3)2CHNCH3Pd(P(C6H5)3)Br)] (89506-21-8)

Guidance literature:

With triphenylphosphine; In not given; smooth react.;; isolation in high yield; detn. by 1H-, 13C-NMR, IR; elem. anal.;;

DOI:10.1016/0022-328X(83)87171-X

Reference yield:

tetrakis(triphenylphosphine) palladium(0) (14221-01-3) + N-methyl-3,4-dimethoxy-6-bromobenzalimine (89525-44-0) → [(C6H2(OCH3)2CHNCH3Pd(P(C6H5)3)Br)] (89506-21-8)

Guidance literature:

In not given; detn. by 1H-, 13C-NMR, IR; elem. anal.;;

DOI:10.1016/0022-328X(83)87171-X

upstream raw materials:

N-methyl-3,4-dimethoxy-6-bromobenzalimine

bis(dibenzylideneacetone)-palladium⁽⁰⁾

tetrakis(triphenylphosphine) palladium⁽⁰⁾

di-μ-bromobis(N-methyl-3,4-dimethoxybenzalimine-6,C,N)dipalladium(II)