(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

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Chemical Name:(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B
CAS No.:864372-82-7
Molecular Formula:C₅₀H₅₀O₁₆P₄
Molecular Weight:1030.83
Hs Code.:

Synonyms:(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

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Chemical Property of (1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

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Technology Process of (1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

There total 8 articles about (1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Phosphoric acid dibenzyl ester (1S,4S,5R,6R)-4-(bis-benzyloxy-phosphoryloxy)-5,6-bis-(1,5-dihydro-benzo[e][1,3,2]dioxaphosphepin-3-yloxy)-cyclohex-2-enyl ester

: 864372-82-7
(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; Yield given; a) -60 deg C, 30 min, b) RT, 1 h;
DOI:10.1021/jm981113k

Reference yield:

: 80582-75-8,174690-27-8
(1R,2R,3R,4R)-anti-benzene dioxide

: 864372-82-7
(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

Guidance literature:: Multi-step reaction with 3 steps

1: 55 percent / CH₂Cl₂ / 12 h

2: 1H-tetrazole / CH₂Cl₂ / 2 h / Ambient temperature

3: m-CPBA / CH₂Cl₂ / a) -60 deg C, 30 min, b) RT, 1 h

With 1H-tetrazole; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/jm981113k

Reference yield:

: 169529-92-4
(+)-(1R,2S,3S,4R)-2,3-dibromocyclohex-5-ene-1,4-diol

: 864372-82-7
(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

Guidance literature:: Multi-step reaction with 4 steps

1: 77 percent / KOH, 4 A molecular sieves / tetrahydrofuran / a) 4 deg C, 1 h, b) RT, 1 h

2: 55 percent / CH₂Cl₂ / 12 h

3: 1H-tetrazole / CH₂Cl₂ / 2 h / Ambient temperature

4: m-CPBA / CH₂Cl₂ / a) -60 deg C, 30 min, b) RT, 1 h

With 1H-tetrazole; potassium hydroxide; 4 A molecular sieve; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jm981113k