D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

Base Information

Chemical Name:D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol
CAS No.:222420-83-9
Molecular Formula:C₅₀H₅₂O₁₈P₄
Molecular Weight:1064.85
Hs Code.:

Synonyms:D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

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Technology Process of D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

There total 9 articles about D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 864372-82-7
(1S,2S,3S,4S)-1,4-bis-O-(di-O-benzylphospho)-2,3-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)conduritol-B

: 222420-83-9
D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

Guidance literature:: With ruthenium trichloride; sodium periodate; In ethyl acetate; acetonitrile; for 0.166667h;
DOI:10.1021/jm981113k

Reference yield:

: 80582-75-8,174690-27-8
(1R,2R,3R,4R)-anti-benzene dioxide

: 222420-83-9
D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

Guidance literature:: Multi-step reaction with 4 steps

1: 55 percent / CH₂Cl₂ / 12 h

2: 1H-tetrazole / CH₂Cl₂ / 2 h / Ambient temperature

3: m-CPBA / CH₂Cl₂ / a) -60 deg C, 30 min, b) RT, 1 h

4: 86 percent / aq. NaIO₄, RuCl₃ / ethyl acetate; acetonitrile / 0.17 h

With 1H-tetrazole; ruthenium trichloride; sodium periodate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1021/jm981113k

Reference yield:

: 169529-92-4
(+)-(1R,2S,3S,4R)-2,3-dibromocyclohex-5-ene-1,4-diol

: 222420-83-9
D-myo-3,6-bis-O-(di-O-benzylphospho)-4,5-bis-O-(2-oxo-5,6-benzo-1,3,2-dioxaphosphep-2-yl)inositol

Guidance literature:: Multi-step reaction with 5 steps

1: 77 percent / KOH, 4 A molecular sieves / tetrahydrofuran / a) 4 deg C, 1 h, b) RT, 1 h

2: 55 percent / CH₂Cl₂ / 12 h

3: 1H-tetrazole / CH₂Cl₂ / 2 h / Ambient temperature

4: m-CPBA / CH₂Cl₂ / a) -60 deg C, 30 min, b) RT, 1 h

5: 86 percent / aq. NaIO₄, RuCl₃ / ethyl acetate; acetonitrile / 0.17 h

With 1H-tetrazole; ruthenium trichloride; potassium hydroxide; sodium periodate; 4 A molecular sieve; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; dichloromethane; ethyl acetate; acetonitrile;
DOI:10.1021/jm981113k