Ruthenium, bis(eta5-2,3,4-trimethylpenta-2,4-dien-1-yl)-

Base Information

Chemical Name:Ruthenium, bis(eta5-2,3,4-trimethylpenta-2,4-dien-1-yl)-
CAS No.:85893-68-1
Molecular Formula:C₁₆H₂₆Ru
Molecular Weight:319.452
Hs Code.:

Synonyms:

Suppliers and Price of Ruthenium, bis(eta5-2,3,4-trimethylpenta-2,4-dien-1-yl)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 3 raw suppliers

Chemical Property of Ruthenium, bis(eta5-2,3,4-trimethylpenta-2,4-dien-1-yl)-

Chemical Property:

PSA：0.00000
LogP:4.61300

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Ruthenium, bis(eta5-2,3,4-trimethylpenta-2,4-dien-1-yl)-

There total 2 articles about Ruthenium, bis(eta5-2,3,4-trimethylpenta-2,4-dien-1-yl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: dichloro-bis-μ-chloro-bis[(1-3η:6-8η)-2,7-dimethyloctadienediyl]diruthenium(II)

: 85893-67-0
2,3,4-trimethyl-1,3-pentadiene

: 85893-68-1
bis(2,3,4-trimethylpentadienyl)ruthenium

Guidance literature:: With Li₂CO₃; In ethanol; acetonitrile; soln. of Ru-complex and 4 equiv. of Li2CO3 in a mixt. of ethanol, 1 equiv. of MeCN and 8 equiv. of ligand were refluxed for 4 h under N2; solvent was evapd., residue was sublimated, elem. anal.;
DOI:10.1021/om0007015

Reference yield:

: 20759-14-2,14898-67-0
ruthenium(III) chloride hydrate

: 85893-67-0
2,3,4-trimethyl-1,3-pentadiene

: 85893-68-1
bis(2,3,4-trimethylpentadienyl)ruthenium

Guidance literature:: With Zn; In ethanol; under N2 Ru salt was added to EtOH with stirring, after which 2,3,4-Me3-1,3-pentadiene was added, then Zn dust was added; stirring at room temp. for ca an h, then refluxing ca 2 h; evapn., , extn. with pentane, cooling to -78°C for several d, sublimation; elem. anal.;
DOI:10.1021/om50003a026