RutheniuM(III) chloride hydrate

Base Information

• Chemical Name: RutheniuM(III) chloride hydrate
• CAS No.: 20759-14-2
• Molecular Formula: Cl3H2ORu
• Molecular Weight: 225.444
• Hs Code.: 2915900090
• Mol file: 20759-14-2.mol

Synonyms:ruthenium trichloride monohydrate;IN3062;

Chemical Property of RutheniuM(III) chloride hydrate

Chemical Property:

• PSA: 9.23000
• LogP: -9.05230
• Storage Temp.: Inert atmosphere,Room Temperature

Purity/Quality:

97% ^*data from raw suppliers

Ruthenium(III) chloride hydrate 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of RutheniuM(III) chloride hydrate

There total 2 articles about RutheniuM(III) chloride hydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

water (7732-18-5) + ruthenium(III)chloride (10049-08-8,63767-78-2) → ruthenium(III) chloride hydrate (20759-14-2,14898-67-0)

Guidance literature:

With HCl; In hydrogenchloride; Electrolysis; soln. of RuCl3 in 2n HCl is electrolysed as catholyte; subsequent concn. of the red soln. in HCl-stream under exclusion of air first at the b.p., later at 80-100°C to dryness;; drying over concd. H2SO4 in vacuum leads to a product free from Ru(IV);;

Reference yield:

ruthenium(IV) hydroxide (12181-34-9) → ruthenium(III) chloride hydrate (20759-14-2,14898-67-0)

Guidance literature:

With hydrogenchloride; In hydrogenchloride; dissolving Ru(OH)4 in HCl (100°C), addn. of H2C2O4; according to Shorikov, Yu. S., et al., Zh. Neorg. Khim., 1984, 29(12), 2999; (Russ. J. Inorg. Chem., 1984(12)); evapn., drying (vac. over alkali, room temp.); elem. anal.;

Reference yield: 99.0%

ruthenium(III) chloride hydrate (20759-14-2,14898-67-0) + N,N'-didodecyl-4,4'-{[2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl)}dibenzamide (841234-02-4) → trichloro(N,N'-didodecyl-4,4'-([2-methoxy-5-(2,2':6',2''-terpyridin-4'-yl)benzene-1,3-diyl]bis(ethyne-2,1-diyl))dibenzamide)ruthenium(III) (841234-12-6)

Guidance literature:

In ethanol; suspn. of RuCl3*H2O and ligand in ethanol was refluxed for 6 h under Ar; cooled; filtered; washed (H2O, EtOH); dried;

DOI:10.1002/hlca.200490262

upstream raw materials:

water

ruthenium(III)chloride

ruthenium(IV) hydroxide

Downstream raw materials:

trans-3-oxospiro[isobenzofuran-1(3H),1'-cyclohexane]-4'-carboxylic acid

[ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂

cis-dichlorobis(2,2′-bipyridine)ruthenium(II)

ruthenium

Refernces

A series of ruthenium(II) complexes containing the bulky, functionalized trialkylphosphines tBu₂PCH₂XC₆H₅ as ligands

10.1039/b106243n

The study focuses on the synthesis and characterization of a series of ruthenium(II) complexes containing bulky, functionalized trialkylphosphines, specifically tBu2PCH2XC6H5, as ligands. These complexes were prepared through reductive routes or ligand replacement reactions, and their structures and properties were investigated. The chemicals used in the study include ruthenium(III) chloride hydrate (RuCl3·3H2O), trialkylphosphines tBu2PCH2XPh (where X = CH2 or OCH2), isoprene, and various other reagents such as AgPF6, acetone, CH3CN, and PMe3. These chemicals served as starting materials, ligands, reducing agents, and solvents in the preparation of the complexes. The purpose of these chemicals was to create a variety of ruthenium(II) complexes that can be used as catalysts in olefin metathesis reactions, with the aim of modifying the coordination sphere of the metal to find potentially better catalysts for these reactions. The study also explored the reactivity of these complexes towards various substrates, such as acetylene, to form new compounds like allenylidene and vinylidene complexes, which were further tested for their catalytic activity in ring-opening metathesis polymerization (ROMP) of cyclooctene.