monocarbonyltris(trimethylphosphine)nickel

Base Information

• Chemical Name: monocarbonyltris(trimethylphosphine)nickel
• CAS No.: 15376-84-8
• Molecular Formula: C₁₀H₂₇NiOP₃
• Molecular Weight: 314.935

Synonyms:monocarbonyltris(trimethylphosphine)nickel

Chemical Property of monocarbonyltris(trimethylphosphine)nickel

Chemical Property:

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Technology Process of monocarbonyltris(trimethylphosphine)nickel

There total 7 articles about monocarbonyltris(trimethylphosphine)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

thiophosgene (463-71-8) + (cyclooctadiene)bis(trimethylphosphino)nickel (101077-61-6) + toluene (108-88-3,15644-74-3,16713-13-6) → monocarbonyltris(trimethylphosphine)nickel (15376-84-8) + Ni2Cl2(CS)(P(CH3)3)3*CH3C6H5

Guidance literature:

In toluene; byproducts: cyclooctadiene; mixing of solns. of CSCl2 and Ni complex (-80°C, stirring), warming to 20°C, stirring (1 h); filtration, volume reduction (vac.), crystn. from oil (3 days), recrystn. (toluene, -70°C); elem. anal.;

DOI:10.1002/(SICI)1521-3773(19980918)37:17<2385::AID-ANIE2385>3.0.CO;2-Y

Reference yield: 32.0%

tetrakis(trimethylphosphine)nickel(0) (28069-69-4) + carbon dioxide (124-38-9,18923-20-1) → monocarbonyltris(trimethylphosphine)nickel (15376-84-8) + Trimethylphosphine oxide (676-96-0)

Guidance literature:

In diethyl ether; at -78 - 20 ℃; for 2h; Inert atmosphere; Schlenk technique;

DOI:10.1016/j.ica.2012.09.002

Reference yield:

tetracarbonyl nickel (13463-39-3,71564-36-8) + trimethylphosphane (594-09-2) → monocarbonyltris(trimethylphosphine)nickel (15376-84-8) + dicarbonylbis(trimethylphosphine)nickel(0) (16787-34-1)

Guidance literature:

react. in mixt. of Ni(CO)4 with 8-fold amt. of P(CH3)3;; IR;

DOI:10.1021/ja00713a007

upstream raw materials:

tetracarbonyl nickel

trimethylphosphane

{((CH₃)3P)2Ni(CH₂C(CH₃)2C₆H₄)}

thallium(I) tetrafluoroborate

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