N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

Base Information

Chemical Name:N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine
CAS No.:1581255-25-5
Molecular Formula:C₃₇H₃₄IN
Molecular Weight:619.588
Hs Code.:

Synonyms:N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

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Chemical Property of N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

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Technology Process of N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

There total 3 articles about N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 355832-04-1
N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine

: 22409-77-4
4,4′-diiodo-2,2′,6,6′-tetramethyl-1,1′-biphenyl

: 1581255-25-5
N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

Guidance literature:: 4,4′-diiodo-2,2′,6,6′-tetramethyl-1,1′-biphenyl; With tri-tert-butyl phosphine; palladium diacetate; In toluene; for 0.25h;

N-phenyl-(9,9-dimethyl-9H-fluoren-2-yl)amine; With sodium t-butanolate; In toluene; at 105 ℃;
DOI:10.1021/cm500602y

Reference yield:

: 28320-31-2
2-bromo-9,9-dimethyl-9H-fluorene

: 1581255-25-5
N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: palladium diacetate; tri-tert-butyl phosphine / toluene / 0.25 h

1.2: 105 °C

2.1: palladium diacetate; tri-tert-butyl phosphine / toluene / 0.25 h

2.2: 105 °C

With tri-tert-butyl phosphine; palladium diacetate; In toluene; 2.1: |Buchwald-Hartwig Coupling / 2.2: |Buchwald-Hartwig Coupling;
DOI:10.1021/cm500602y

Reference yield:

: 62-53-3
aniline

: 1581255-25-5
N-(4′-iodo-2,2′,6,6′-tetramethyl-[1,1′-biphenyl]-4-yl)-9,9-dimethyl-N-phenyl-9H-fluoren-3-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: palladium diacetate; tri-tert-butyl phosphine / toluene / 0.25 h

1.2: 105 °C

2.1: palladium diacetate; tri-tert-butyl phosphine / toluene / 0.25 h

2.2: 105 °C

With tri-tert-butyl phosphine; palladium diacetate; In toluene; 2.1: |Buchwald-Hartwig Coupling / 2.2: |Buchwald-Hartwig Coupling;
DOI:10.1021/cm500602y