zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin

Base Information

• Chemical Name: zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin
• CAS No.: 117256-47-0
• Molecular Formula: C₄₃H₂₇N₅Zn
• Molecular Weight: 679.111
• Mol file: 117256-47-0.mol

Synonyms:zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin

Chemical Property of zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin

There total 4 articles about zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

5-(4-pyridyl)-10,15,20-triphenylporphyrin + zinc diacetate (557-34-6) → zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin (117256-47-0)

Guidance literature:

In methanol; chloroform; refluxing ligand (in CHCl3) with 2 equiv. Zn-salt (in MeOH) for 30 min; concn., MeOH addn., crystn. (-20°C, 8 h), collection (filtration), washing (cold MeOH);

Reference yield:

5-(4-pyridyl)-10,15,20-triphenylporphyrin + zinc(II) chloride (7646-85-7,24359-56-6) → zinc(II) meso-5-(4-pyridyl)-10,15,20-triphenylporphyin (117256-47-0)

Guidance literature:

In N,N-dimethyl-formamide; refluxing; purified by chromy. on silica (silica gel 60) with chloroform, purity >99%;

DOI:10.1021/jp0044227

Reference yield:

5-(4-pyridyl)-10,15,20-triphenylporphyrin semihydrate + zinc diacetate (557-34-6) → 5-pyridyl-10,15,20-triphenylporphyrinatozinc(II) (117256-47-0)

Guidance literature:

In N,N-dimethyl-formamide; addn. of an excess of zinc acetate to 5-pyridyl-10,15,20-triphenylporphyrin in DMF; refluxing for 1 h;; removal of solvent; chromy. (silica gel, CHCl3/ethanol solvent system);;

upstream raw materials:

zinc diacetate

zinc(II) chloride

Downstream raw materials:

zinc 5-(N-(4-bromomethylbenzyl)-4-pyridinio)-10,15,20-triphenylporphyrinate hexafluorophosphate

Ru(II)(2,3,7,8,12,13,17,18-octaethylporphyrinato)(CO)(Zn(5-(4-pyridyl)-10,15,20-triphenylporphyrinate))