(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

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Chemical Name:(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one
CAS No.:681121-49-3
Molecular Formula:C₅₁H₉₄O₆Si₂
Molecular Weight:859.475
Hs Code.:

(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

Synonyms:(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

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Chemical Property of (R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

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Technology Process of (R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

There total 4 articles about (R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 681121-50-6
(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2R,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

: 681121-49-3
(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

Guidance literature:: With potassium carbonate; In tetrahydrofuran; methanol; at 20 ℃; for 5h;
DOI:10.1021/jo0303721

Reference yield:

: (Z)-(1R,14R)-15-Benzyloxy-14-(tert-butyl-dimethyl-silanyloxy)-1-{(R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-pentadec-5-en-1-ol

: 681121-49-3
(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

Guidance literature:: Multi-step reaction with 4 steps

1: m-CPBA; Na₂HPO₄ / CH₂Cl₂ / 1.17 h / 20 °C

2: CSA / CH₂Cl₂ / 0.92 h / 20 °C

3: TPAP; 4 Angstroem molecular sieves; NMO / acetonitrile; CH₂Cl₂ / 2 h / 20 °C

4: 73 percent / K₂CO₃ / methanol; tetrahydrofuran / 5 h / 20 °C

With disodium hydrogenphosphate; N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; camphor-10-sulfonic acid; potassium carbonate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran; methanol; dichloromethane; acetonitrile;
DOI:10.1021/jo0303721

Reference yield:

: (R)-4-{3-[(R)-9-Benzyloxy-8-(tert-butyl-dimethyl-silanyloxy)-nonyl]-oxiranyl}-1-{(R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-butan-1-ol

: 681121-49-3
(R)-10-Benzyloxy-9-(tert-butyl-dimethyl-silanyloxy)-1-((2S,6R)-6-{(2R,5R)-5-[(R)-1-(tert-butyl-dimethyl-silanyloxy)-tridecyl]-tetrahydro-furan-2-yl}-tetrahydro-pyran-2-yl)-decan-1-one

Guidance literature:: Multi-step reaction with 3 steps

1: CSA / CH₂Cl₂ / 0.92 h / 20 °C

2: TPAP; 4 Angstroem molecular sieves; NMO / acetonitrile; CH₂Cl₂ / 2 h / 20 °C

3: 73 percent / K₂CO₃ / methanol; tetrahydrofuran / 5 h / 20 °C

With N-methyl-2-indolinone; tetrapropylammonium perruthennate; 4 A molecular sieve; camphor-10-sulfonic acid; potassium carbonate; In tetrahydrofuran; methanol; dichloromethane; acetonitrile;
DOI:10.1021/jo0303721