Technology Process of 12-benzyloxypodocarpa-8,11,13-triene-6α,19-diol
There total 6 articles about 12-benzyloxypodocarpa-8,11,13-triene-6α,19-diol which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium tetrahydroborate;
In
tetrahydrofuran; water;
-
-
55025-16-6
methyl (1S,4aS,10aR)-6-(benzyloxy)-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-1-carboxylate
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 84 percent / chromium trioxide, acetic acid / 22 h
2: 91 percent / sodium borohydride / tetrahydrofuran; H2O / 24 h
3: 81 percent / HCl / methanol / 5 h / Heating
4: 1.) borane, dimethyl sulfide, 2.) H2O2, sodium hydroxide / 1.) THF, 3.5 h, 2.) THF, water, 50 deg, 1 h
5: 80 percent / sodium borohydride / tetrahydrofuran; H2O
With
chromium(VI) oxide; hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; dimethylsulfide; borane; dihydrogen peroxide; acetic acid;
In
tetrahydrofuran; methanol; water;
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 91 percent / sodium borohydride / tetrahydrofuran; H2O / 24 h
2: 81 percent / HCl / methanol / 5 h / Heating
3: 1.) borane, dimethyl sulfide, 2.) H2O2, sodium hydroxide / 1.) THF, 3.5 h, 2.) THF, water, 50 deg, 1 h
4: 80 percent / sodium borohydride / tetrahydrofuran; H2O
With
hydrogenchloride; sodium hydroxide; sodium tetrahydroborate; dimethylsulfide; borane; dihydrogen peroxide;
In
tetrahydrofuran; methanol; water;
