2-Methylbenzo(c)phenanthrene

Base Information

• Chemical Name: 2-Methylbenzo(c)phenanthrene
• CAS No.: 2606-85-1
• Molecular Formula: C19H14
• Molecular Weight: 242.32
• Hs Code.: 2902909090
• European Community (EC) Number: 660-715-4
• NSC Number: 171295
• UNII: 8DFC8R9Z8R
• DSSTox Substance ID: DTXSID10180701
• Nikkaji Number: J36.042B
• Wikidata: Q27270225
• Mol file: 2606-85-1.mol

Synonyms:2-Methylbenzo(c)phenanthrene;2-Methylbenzo[c]phenanthrene;2-Methyl-3,4-benzophenanthrene;2606-85-1;6-Methyl-3:4-benzphenanthrene;BENZO(c)PHENANTHRENE, 2-METHYL-;Benzo[c]phenanthrene, 2-methyl-;UNII-8DFC8R9Z8R;NSC 171295;BRN 1872511;8DFC8R9Z8R;NSC-171295;NSC171295;6-Methyl-3,4-benzphenanthren;Cc1ccc2ccc3ccc4ccccc4c3c2c1;DTXSID10180701;WLN: L C6 B666J E1;AKOS024340892;LS-38829;Q27270225

Chemical Property of 2-Methylbenzo(c)phenanthrene

Chemical Property:

• Vapor Pressure: 7.61E-08mmHg at 25°C
• Melting Point: 81.75°C
• Refractive Index: 1.4750 (estimate)
• Boiling Point: 449.4°Cat760mmHg
• Flash Point: 217.8°C
• PSA: 0.00000
• Density: 1.164g/cm³
• LogP: 5.45460
• XLogP3: 6.4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 242.109550447
• Heavy Atom Count: 19
• Complexity: 320

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC2=C(C=C1)C=CC3=C2C4=CC=CC=C4C=C3

Technology Process of 2-Methylbenzo(c)phenanthrene

There total 20 articles about 2-Methylbenzo(c)phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

2-methyl-5,6,7,8-tetrahydrobenzo[c]phenanthrene (1047647-79-9) → 2-methylbenzo[c]phenanthrene (2606-85-1)

Guidance literature:

With 10% Pd/C; In 1,3,5-trimethyl-benzene; for 9h; Reflux;

DOI:10.1002/anie.200801396

Reference yield: 96.0%

2-[2-(4-methylphenyl)-(E)-ethenyl]-naphthalene (35160-96-4,845624-67-1) → 2-methylbenzo[c]phenanthrene (2606-85-1)

Guidance literature:

With iodine; In tetrahydrofuran; toluene; for 20h; Irradiation;

DOI:10.3998/ark.5550190.0012.902

Reference yield: 82.0%

2-(4-methylstyryl)naphthalene (35160-96-4,845624-67-1) → 2-methylbenzo[c]phenanthrene (2606-85-1)

Guidance literature:

Irradiation;

DOI:10.1021/acs.joc.7b03234

upstream raw materials:

methyl magnesium iodide

4,4a,5,6-tetrahydro-3H-benzo[c]phenanthren-2-one

2-methyl-5,6,6a,7,8,12b-hexahydro-benzo[c]phenanthrene

2-(4-methylstyryl)naphthalene

Downstream raw materials:

benzo[c]phenathrene

cyclopenta[c,d]pyrene

benzo[ghi]fluoranthene

5-methylbenzo[ghi]fluoranthene

Refernces

• 1、 Jakubec, Martin,Beránek, Tomá?,Jakubík, Pavel,Sykora, Jan,?ádny, Jaroslav,Církva, Vladimír,Storch, Jan. "2-Bromo[6]helicene as a Key Intermediate for [6]Helicene Functionalization". . p. 3607 - 3616. Retrieved 2018/04/14.
• 2、 Fuchibe, Kohei,Jyono, Hideharu,Fujiwara, Masaki,Kudo, Takao,Yokota, Misaki,Ichikawa, Junji. "Domino Friedel-crafts-type cyclizations of difluoroalkenes promoted by the α-cation-stabilizing effect of fluorine: An efficient method for synthesizing angular PAHs". scheme or table. p. 12175 - 12185. Retrieved 2011/12/01.