2-amino-3-(benzylideneamino)-2-butenedinitrile

Base Information

Chemical Name:2-amino-3-(benzylideneamino)-2-butenedinitrile
CAS No.:946529-80-2
Molecular Formula:C₁₁H₈N₄
Molecular Weight:196.211
Hs Code.:
Mol file:946529-80-2.mol

Synonyms:(2Z)-2-Amino-3-{[(1E)-(phenyl)methylidene]-amino}but-2-enedinitrile

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-amino-3-(benzylideneamino)-2-butenedinitrile

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Technology Process of 2-amino-3-(benzylideneamino)-2-butenedinitrile

There total 1 articles about 2-amino-3-(benzylideneamino)-2-butenedinitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 100-52-7
benzaldehyde

: 1187-42-4
diaminomaleonitrile

: 946529-80-2
(2Z)-2-Amino-3-{[(1E)-(phenyl)methylidene]-amino}but-2-enedinitrile

Guidance literature:: With toluene-4-sulfonic acid; In ethanol; at 20 ℃; for 2h;
DOI:10.1021/jo0707131

Reference yield:

: 946529-80-2
(2Z)-2-Amino-3-{[(1E)-(phenyl)methylidene]-amino}but-2-enedinitrile

: 51802-03-0
N-Benzyldiaminomaleonitrile

Guidance literature:: With sodium tetrahydroborate; In tetrahydrofuran; methanol;
DOI:10.1016/j.tet.2005.03.090

Reference yield:

: 946529-80-2
(2Z)-2-Amino-3-{[(1E)-(phenyl)methylidene]-amino}but-2-enedinitrile

: C₇₂H₈₄N₁₀^(2-)*Mg⁽²⁺⁾

Guidance literature:: Multi-step reaction with 5 steps

1.1: NaBH₄ / methanol; tetrahydrofuran

2.1: methanol / Heating

3.1: NaBH₄ / methanol; tetrahydrofuran

4.1: NaH / tetrahydrofuran / 0.5 h / -22 °C

4.2: 80 percent / tetrahydrofuran / 4 h / -22 - 20 °C

5.1: Mg; n-BuOH; I₂ / 24 h / Heating

With sodium tetrahydroborate; iodine; sodium hydride; magnesium; butan-1-ol; In tetrahydrofuran; methanol;
DOI:10.1016/j.tet.2005.03.090