[cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

Base Information

Chemical Name:[cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide
CAS No.:497155-65-4
Molecular Formula:C₁₉H₃₁NO₆
Molecular Weight:369.458
Hs Code.:

Synonyms:[cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

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Chemical Property of [cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

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Technology Process of [cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

There total 3 articles about [cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 35023-80-4
2,3:5,6-di-O-isopropylidene-D-mannose oxime

: 2043-61-0
cyclohexanecarbaldehyde

: 497155-65-4
[cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

Guidance literature:: With magnesium sulfate; In dichloromethane; at 23 ℃; for 18h;
DOI:10.1002/anie.200461934

Reference yield: 76.0%

: 104320-20-9
2,3:5,6-di-O-isopropylidene-D-mannose oxime

: 2043-61-0
cyclohexanecarbaldehyde

: 497155-65-4
[cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

Guidance literature:: With sodium sulfate; In dichloromethane; at 23 ℃; for 120h;
DOI:10.1021/ol052331s

Reference yield:

: 7757-38-2,14131-84-1,23262-78-4,27108-13-0,33823-04-0,34685-42-2,57819-52-0,78039-08-4,78039-12-0,78964-16-6,94842-76-9,149342-31-4
2,3,5,6-di-O-isopropylidene-D-mannofuranose

: 497155-65-4
[cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide

Guidance literature:: Multi-step reaction with 2 steps

1: 60.3 g / N-hydroxylamine hydrochloride; NaOAc / ethanol / 1 h / Heating

2: 76 percent / Na₂SO₄ / CH₂Cl₂ / 120 h / 23 °C

With hydroxylamine hydrochloride; sodium acetate; sodium sulfate; In ethanol; dichloromethane;
DOI:10.1021/ol052331s