104320-20-9

Basic information

• Product Name: DIACETONE MANNOSEOXIME
• Synonyms: DIACETONE MANNOSEOXIME
• CAS NO: 104320-20-9
• Molecular Formula: C₁₂H₂₁NO₆
• Molecular Weight: 275.3
• Mol File: 104320-20-9.mol
• Article Data: 4

Chemical Properties

• Appearance: /
• CAS DataBase Reference: DIACETONE MANNOSEOXIME(CAS DataBase Reference)
• NIST Chemistry Reference: DIACETONE MANNOSEOXIME(104320-20-9)
• EPA Substance Registry System: DIACETONE MANNOSEOXIME(104320-20-9)

Safety Data

• Hazardous Substances Data: 104320-20-9(Hazardous Substances Data)

Upstream product

• 13199-23-0 O²,O³;O⁵,O⁶-diisopropylidene-D-gulose 
• 6322-07-2 D-gulono-1,4-lactone 
• 260441-81-4 2,3:5,6-di-O-isopropylidene-D-gulose oxime 
• 78039-08-4 2,3:5,6-di-O-isopropylidene-α-D-gulono-furanose 
• 7757-38-2 2,3,5,6-di-O-isopropylidene-D-mannofuranose 
• 78039-12-0 (3aR,4R,6S,6aR)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydro-furo[3,4-d][1,3]dioxol-4-ol 
• 14686-89-6 (1,2:5,6)-di-O-isopropylidene-D-gulose 
• 26775-14-4 3-O-acetyl-1,2:5,6-di-O-isopropylidene-α-D-gulofuranose 
• 14686-88-5 3-O-acetyl-1,2:5,6-di-O-isopropylidene-α-D-erythro-hex-3-enofuranose 
• 67642-42-6 2,3,5,6-di-O-isopropylidene-D-gulono-1,4-lactone 

Downstream Products

• 497155-65-4 [cyclohexylmeth-(Z)-ylidene][(3aS,4S,6R,6aS)-6-((R)-2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl]amine N-oxide 
• 1370639-67-0 C₂₈H₄₃NO₉ 

Relevant articles and documents

ZnCl2-mediated stereoselective addition of terminal alkynes to D-(+)-mannofuranosyl nitrones

(Chemical Equation Presented) An optimized process for the addition of terminal alkynes to chiral nitrones using ZnCl2 and NEt3 in toluene is reported. The new reaction protocol is facile to perform and cost-effective. The resulting

Enantioselective, chromatography-free synthesis of β3-Amino acids with natural and unnatural side chains

β3-Amino acids are key components of some pharmaceuticals, excellent surrogates for metabolically labile α-amino acids, and building blocks for chiral heterocycles. Unfortunately they are not easily accessible in enantiomerically pure form, especially when possessing unnatural side chains. A flexible, chromatography-free process for the synthesis of enantiopure β3-amino acids possessing natural and unnatural side chains is described. The procedure uses inexpensive starting materials and reagents and offers a good alternative to the hazardous and expensive Arndt-Eistert homologation of enantiopure α-amino acids. Its utility has been demonstrated with the preparative scale synthesis of two valuable β3-amino acids possessing unnatural side chains.