2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

Base Information

Chemical Name:2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone
CAS No.:142067-72-9
Molecular Formula:C₄₆H₃₈O₇
Molecular Weight:702.804
Hs Code.:

Synonyms:2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

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Chemical Property of 2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

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Technology Process of 2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

There total 8 articles about 2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 142067-77-4
(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

: 142067-72-9
2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

Guidance literature:: With ammonium cerium(IV) nitrate; In tetrahydrofuran; water; at 23 ℃; Yield given;
DOI:10.1021/ja00040a057

Reference yield:

: 871-84-1
1,7-Octadiyne

: 142067-72-9
2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

Guidance literature:: Multi-step reaction with 6 steps

1: 1.) n-butyllithium / 1.) THF, 0 deg C, 2.) THF, 23 deg C, 12 h

2: 40 percent / 2Cl₃(THF)6>22Cl₆>, DMF / CH₂Cl₂ / 23 °C

3: 79 percent / triethylamine, 4-(N,N-dimethylamino)pyridine (DMAP) / CH₂Cl₂

4: Dess-Martin periodinane / CH₂Cl₂ / 23 °C

5: 1.) n-butyllithium / 1.) THF, -78 deg C, 20 min

6: ceric ammonium nitrate / tetrahydrofuran; H₂O / 23 °C

With dmap; n-butyllithium; ammonium cerium(IV) nitrate; 2; Dess-Martin periodane; triethylamine; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ja00040a057

Reference yield:

: 99058-82-9
2,8-decadiynedial

: 142067-72-9
2-{(1R,10R)-1-Hydroxy-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynyl}-1,4-dimethoxy-anthraquinone

Guidance literature:: Multi-step reaction with 5 steps

1: 40 percent / 2Cl₃(THF)6>22Cl₆>, DMF / CH₂Cl₂ / 23 °C

2: 79 percent / triethylamine, 4-(N,N-dimethylamino)pyridine (DMAP) / CH₂Cl₂

3: Dess-Martin periodinane / CH₂Cl₂ / 23 °C

4: 1.) n-butyllithium / 1.) THF, -78 deg C, 20 min

5: ceric ammonium nitrate / tetrahydrofuran; H₂O / 23 °C

With dmap; n-butyllithium; ammonium cerium(IV) nitrate; 2; Dess-Martin periodane; triethylamine; N,N-dimethyl-formamide; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/ja00040a057