(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

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Chemical Name:(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol
CAS No.:142067-77-4
Molecular Formula:C₅₈H₆₈O₇Si₂
Molecular Weight:933.345
Hs Code.:

Synonyms:(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

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Chemical Property of (1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

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Technology Process of (1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

There total 7 articles about (1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 871-84-1
1,7-Octadiyne

: 142067-77-4
(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) n-butyllithium / 1.) THF, 0 deg C, 2.) THF, 23 deg C, 12 h

2: 40 percent / 2Cl₃(THF)6>22Cl₆>, DMF / CH₂Cl₂ / 23 °C

3: 79 percent / triethylamine, 4-(N,N-dimethylamino)pyridine (DMAP) / CH₂Cl₂

4: Dess-Martin periodinane / CH₂Cl₂ / 23 °C

5: 1.) n-butyllithium / 1.) THF, -78 deg C, 20 min

With dmap; n-butyllithium; 2; Dess-Martin periodane; triethylamine; N,N-dimethyl-formamide; In dichloromethane;
DOI:10.1021/ja00040a057

Reference yield:

: 99058-82-9
2,8-decadiynedial

: 142067-77-4
(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

Guidance literature:: Multi-step reaction with 4 steps

1: 40 percent / 2Cl₃(THF)6>22Cl₆>, DMF / CH₂Cl₂ / 23 °C

2: 79 percent / triethylamine, 4-(N,N-dimethylamino)pyridine (DMAP) / CH₂Cl₂

3: Dess-Martin periodinane / CH₂Cl₂ / 23 °C

4: 1.) n-butyllithium / 1.) THF, -78 deg C, 20 min

With dmap; n-butyllithium; 2; Dess-Martin periodane; triethylamine; N,N-dimethyl-formamide; In dichloromethane;
DOI:10.1021/ja00040a057

Reference yield:

: 142067-64-9,142067-68-3
Cyclodeca-3,9-diyne-1,2-diol

: 142067-77-4
(1R,10R)-1-[9,10-Bis-(tert-butyl-dimethyl-silanyloxy)-1,4-dimethoxy-anthracen-2-yl]-10-[(4-methoxy-phenyl)-diphenyl-methoxy]-cyclodeca-2,8-diynol

Guidance literature:: Multi-step reaction with 3 steps

1: 79 percent / triethylamine, 4-(N,N-dimethylamino)pyridine (DMAP) / CH₂Cl₂

2: Dess-Martin periodinane / CH₂Cl₂ / 23 °C

3: 1.) n-butyllithium / 1.) THF, -78 deg C, 20 min

With dmap; n-butyllithium; Dess-Martin periodane; triethylamine; In dichloromethane;
DOI:10.1021/ja00040a057