4-methyl-pentyl hydroperoxide

Base Information

• Chemical Name: 4-methyl-pentyl hydroperoxide
• CAS No.: 52387-48-1
• Molecular Formula: C₆H₁₄O₂
• Molecular Weight: 118.176
• Mol file: 52387-48-1.mol

Synonyms:4-methyl-pentyl hydroperoxide

Chemical Property of 4-methyl-pentyl hydroperoxide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-methyl-pentyl hydroperoxide

There total 1 articles about 4-methyl-pentyl hydroperoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-Methylpentane (107-83-5) → 1,1-dimethylbutyl hydroperoxide (13393-68-5) + 2-methyl-1-pentylhydroperoxide (42081-81-2) + 4-methyl-pentyl hydroperoxide (52387-48-1) + 4-hydroperoxy 2-methylpentane (54942-19-7)

Guidance literature:

With n-Bu₄VO₃; dihydrogen peroxide; oxygen; PDCA; In acetonitrile; at 40 ℃; Further Variations:; Reagents; Product distribution;

DOI:10.1039/b101442k

Reference yield:

4-methyl-pentyl hydroperoxide (52387-48-1) → 4-methyl-4-penten-1-ol (22508-64-1)

Guidance literature:

With copper diacetate; iron(II) sulfate; In acetic acid;

DOI:10.1016/S0040-4020(01)88972-9

Reference yield:

4-methyl-pentyl hydroperoxide (52387-48-1) → (((4-fluoro-4-methylpentyl)oxy)methyl)benzene

Guidance literature:

Multi-step reaction with 2 steps

1: N-fluorobis(benzenesulfon)imide; chloro(5,10,15,20-tetra-1-naphtylporphyrinato)iron(III); lithium borohydride; 4-methoxy-phenol / acetonitrile / 0.08 h / 20 °C / Glovebox

2: sodium hydride / 0 - 20 °C

With lithium borohydride; chloro(5,10,15,20-tetra-1-naphtylporphyrinato)iron(III); sodium hydride; 4-methoxy-phenol; N-fluorobis(benzenesulfon)imide; In acetonitrile;

DOI:10.1002/anie.201806434

upstream raw materials:

2-Methylpentane

Downstream raw materials:

4-methyl-4-penten-1-ol